1. 毕业设计（论文）的内容和要求

氢化镁因其储氢量高(7.6 wt.%)，原料来源丰富，对环境影响小等优点而被认为是一种可应用于氢燃料电池的理想储氢材料。

然而氢化镁放氢热力学性能较差，通常需要在较高温度(573 k)下才可放氢，阻碍了氢化镁的实际应用。

近年来，氢化镁水解释氢研究吸引了众多研究者，因为氢化镁水解释氢可在常温下进行，且放氢量高达15.2wt.%(或1703 ml/g)。

2. 参考文献

[1] 毛宗强. 氢能-21世纪的绿色能源[M]. 北京：化学工业出版社, 2005. [2] 程谋森, 刘 昆, 张育林. 液氢/液氧的应用前景[J]. 世界导弹与航天, 1990: 40-41. [3] 李立权. 加氢技术的最新进展及分类探索[J]. 石油与天然气化工, 2002, 31:116-118. [4] 李国栋,张秀玲,胡仰栋. 电子级多晶硅生产工艺的热力学分析[J]. 过程工程学报, 2007, 7:520-525. [5] 福特公司网. 福特汽车在上海推出世界最清洁的内燃机. http: //www. ford. com. cn, 2004. [6] Akgawa H, Ishida H, Osafune S, et al. Development of hydrogen injection clean engine [C]: Proceedings of the 15th World Hydrogen Energy Conference. Yokohama: 2004. [7] 赫麦罗夫, 拉夫罗夫. 氢内燃机[M]. 北京: 新时代出版社, 1987. [8] 杨振中. 氢燃料发动机燃烧与优化控制[D]. 杭州：浙江大学, 2001. [9] 边耀璋. 汽车新能源技术[M]. 北京:人民交通出版社, 2003. [10] 詹姆斯#183;拉米尼，安德鲁#183;迪克斯. 燃料电池系统-原理#183;设计#183;应用[M]. 北京：科学出版社, 2006. [11] Mori D, Hirose D. Recent challenges of hydrogen storage technologies for fuel cell vehicles[J]. International Journal of Hydrogen Energy, 2009, 34:4569-4574. [12] Eberle U, M#252;ller B, Helmolt V. Fuel cell electric vehicles and hydrogen infrastructure: status 2012 [J]. Energy Environmental Science, 2012, 5: 8780-8798. [13] 肖九梅. 氢燃料电池汽车及其电池现状[J]. 电力电子, 2013:50-54. [14] Micro M. Samsung Link up for portable electronics[J]. Fuel Cells Bulletin, 2006, 2006:1. [15] Stojcev M. Portable electronics product design and development[J]. Microelectronics Reliability, 2008, 48:333-334. [16] Chang H P, Chou C L, Chen Y S, et al. The Design and cost analysis of a portable PEMFC UPS system[J]. International Journal of Hydrogen Energy, 2007, 32: 316~322. [17] DoCoMo N. Aquafairy develop micro hydrogen fuel cell for FOMA cell phone handsets[J]. Fuel Cells Bulletin, 2006, 2006:1. [18] Launches T. High-power portable fuel cell[J]. Fuel Cells Bulletin, 2007, 2007:6. [19] Demos A. Micro fuel cell in handsets[J]. Fuel Cells Bulletin, 2008, 2008:6. [20] Park J T, Xu X R, Wang J, et al. A small-scale and portable 50 W PEMFC system that automatically generates hydrogen from a mixture of Al, CaO, NaOH and sodium CMC in water without external power supply[J]. International Journal of Hydrogen Energy, 2013, 38:10511-10518. [21] 王纪忠，王靖，朴延泰. 使用制氢剂及便携式高分子燃料电池的小型发电机. 中国: CN102324794A [P], 2011. [22] 氢能协会[日]. 氢能技术[M]. 宋永臣, 宁亚东, 金东旭, 译. 北京: 科学出版社, 2009. [23] Xu Y, Chun D H, Jang J H, et al. Catalytic activity of oxidation-reduction pre-treated Ni3Al for methane steam reforming[J]. Advanced Materials Research, 2010, 89:645-650. [24] Str#246;bel R, Garche J, Moseley P T, et al. Hydrogen storage by carbon materials[J]. Journal of Power Sources, 2006, 159:781-801. [25] Tamura T, Tominaga Y, Matsumoto K, et al. Protium absorption properties of Ti#8211;V#8211;Cr#8211;Mn alloys with a b.c.c. structure[J]. Journal of Alloys and Compounds, 2002, 330#8211;332:522-525. [26] Sifer N, Gardner K. An analysis of hydrogen production from ammonia hydride hydrogen generators for use in military fuel cell environments[J]. Journal of Power Sources, 2004, 132:135-138. [27] Kreevoy M M, Jacobson R W. The rate of decomposition of sodium borohydride in basic aqueous solution[J]. Ventron Alembic, 1979, 15:2-3. [28] Minkina V G, Shabunya S I, Kalinin V I, et al. Long-term stability of sodium borohydrides for hydrogen generation[J]. International Journal of Hydrogen Energy, 2008, 33:5629-5635. [29] Liu C H, Chen B H, Hsueh C L, et al. Hydrogen genenration from hydrolysis of sodium borohydride using Ni-Ru nanocomposite as catalysts[J]. International Journal of Hydrogen Energy, 2009, 34:2153-2163. [30] Su C C, Lu M C, Wang S L, et al. Ruthenium immobilized on Al2O3 pellets as a catalyst for hydrogen generation from hydrolysis and methanolysis of sodium borohydride[J]. RSC Advances, 2012, 2:2073-2079.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2015.12.22~ 2015.12.31 中国期刊网、维普数据库以及Elsevier数据库等数据库查阅国内外相关文献 2016.1.04 ~ 2016.1.15 撰写开题报告，开题报告答辩 2016.3.14 ~ 2016.4.5 HCS法制备高活性高容量氢化镁 2016.4.6 ~ 2016.4.19 中期检查与答辩 2016.4. 20~ 2016.5.10 MM法制备高活性氢化镁 五一放假 2016.5.11 ~ 2016.5.15 HCS MM法制备的氢化镁水解性能测试及溶液pH值变化情况，总结出两者之间的关系 2016.5.16~ 2016.5.29 撰写毕业论文 2016.5.30~ 2016.6.5 完成毕业论文及答辩 2016.6.6~ 2016.6.14 总结、归档