1. 毕业设计（论文）的内容和要求

苄基化合物的c-h氧化是近年来有机合成领域研究的热点之一。

通过该研究，学生可学习科研的主要方法。

在查阅文献的基础上制定科学合理的实验方案并予以实施。

2. 参考文献

[1]端木丹丹,梁柏健,蒋其柏,燕红.钯催化苄基的C(sp~3)#8212;H键活化合成芳酸苄酯[J].有机化学,2017,37(10):2669-2677. [2]刘良先,陈密峰,蔡崑.ACC对羰基化合物、含苄基化合物及稠环芳烃中活泼碳氢键的选择性氧化[J].高等学校化学学报,1993(06):809-811. [3]潘英萍.甲苯催化氧化合成苯甲醛的研究[J].黑龙江科技信息,2016(05):41. [4]张金峰.对叔丁基甲苯催化氧化合成对叔丁基苯甲醛工艺研究[J].印染助剂,2017,34(08):38-40. [5]徐阳阳,刘自力,熊小龙,崔斌.V-Mo-O催化剂的制备及催化甲苯合成苯甲醛的研究[J].分子催化,2014,28(01):39-46. [6]李贵贤,王广,毛丽萍,马重华,高云艳,宋维维.固载化杂多酸钴盐催化氧化甲苯制备苯甲醛[J].硅酸盐学报,2011,39(02):359-364. [7]佟惠娟.甲苯氧化成苯甲醛催化剂的合成与反应性能[J].石油化工高等学校学报,1996(02):37-41. [8]唐盛伟,梁斌,吴潘,张全忠,刘长军.甲苯液相空气氧化过程中苯甲醛生成的影响因素分析[J].四川大学学报(工程科学版),2005(05):76-81. [9]祝敬民,严之光,吴指南.甲苯气相催化氧化合成苯甲醛的动力学[J].催化学报,1982(03):180-186. [10]李国防,胡春华,赵文献,郭保国.甲苯制备苯甲醛合成工艺的改进[J].化学试剂,2010,32(06):561-564. [11]张宇飞,朱燕群,王树荣,岑可法.甲苯的光氧化降解试验研究[J].环境科学学报,2015,35(09):2759-2765. [12]Sun H , Chen S , Wang P , et al. Catalytic oxidation of toluene over manganese oxide octahedral molecular sieves (OMS-2) synthesized by different methods[J]. Chemical Engineering Journal, 2011, 178(none):191-196. [13]Shaabani A , Mirzaei P , Naderi S , et al. Green Oxidations. The Use of Potassium Permanganate Supported on Manganese Dioxide.[J]. Tetrahedron, 2004, 60(50):11415-11420. [14]Shaabani A , Bazgir A , Teimouri F , et al. Selective oxidation of alkylarenes in dry media with potassium permanganate supported on Montmorillonite K10[J]. Tetrahedron Letters, 2002, 43(29):5165-5167. [15]Tripathy J , Lee K , Schmuki P . Tuning the Selectivity of Photocatalytic Synthetic Reactions Using Modified TiO , 2 , Nanotubes[J]. Angewandte Chemie, 2014, 126(46):12813-12816. [16]Shaabani A , Tabatabaei A T , Hajishaabanha F , et al. KMnO 4 /guanidinium-based sulfonic acid: as an efficient Broslash;nsted acid organocatalyst for the selective oxidation of organic compounds[J]. Journal of Sulfur Chemistry, 2018:1-13. [17]Aghbolaghy M , Soltan J , Chen N . Role of Surface Carboxylates in the Gas Phase Ozone-Assisted Catalytic Oxidation of Toluene[J]. Catalysis Letters, 2017, 147(9):1-13. [18]Tanase S , Reedijk J , Hage R , et al. Hydrocarbon Oxidation with H2O2, Catalyzed by Iron Complexes with a Polydentate Pyridine-Based Ligand[J]. Topics in Catalysis, 2010, 53(15-18):1039-1044. [19]Mandi U , Pramanik M , Roy A S , et al. Chromium(vi) grafted mesoporous polyaniline as a reusable heterogeneous catalyst for oxidation reactions in aqueous medium[J]. Rsc Advances, 2014, 4(30):15431-15440. [9]Bhardwaj M , Sharma H , Paul S , et al. Fe3O4@SiO2/EDAC-Pd(0) as a novel and efficient inorganic/organic magnetic composite: Sustainable catalyst for the benzylic C-H bond oxidation and reductive amination under mild conditions[J]. New J. Chem. 2016:10.1039.C5NJ03413B. [20]Akhlaghinia B , Zarghani M . Fe3O4 magnetic nanoparticles (MNPs) as an efficient catalyst for selective oxidation of benzylic and allylic C-H bonds to carbonyl compounds with tert-butyl hydroperoxide[J]. RSC Advances, 2016, 6(45):38592-38601.

3. 毕业设计（论文）进程安排

2018.12 布置课题 2019.01.15前完成开题报告 2019.02.25-2019.03.10 完成实验方案的制定及实验前 期准备工作 2019.03.11-2019.05.30完成实验工作 2019.06.01-2019.06.10撰写论文，准备答辩。