1. 毕业设计（论文）的内容和要求

碳碳键是分子内大量存在的化学键。

选择性的碳碳键活化官能团化是化学界公认的难题。

而过渡金属催化为解决这一难题提供了新思路。

2. 参考文献

[1] Anhua Hu, Yilin Chen. Cerium-catalyzed Formal Cycloaddition of Cycloalkanols with Alkenes through Dual Photoexcitation [J]. J. Am. Chem. Soc.,2018, 140(42): 13580-13585 [2] Anhua Hu, Jing-Jing Guo. Selective functionalization of methane, ethane, and higher alkanes by cerium photocatalysis [J]. Science, 2018, 361(6403): 668-672 [3] Jose B. Roque, Yusuke Kuroda. Deconstructive fluorination of cyclic amines by carbon-carbon cleavage [J]. Science, 2018,361:171#8211;174 [4] Xiao-Ye Yu, Peng-Zi Wang. Photocatalytic Neophyl Rearrangement and Reduction of Distal Carbon Radicals by Iminyl Radical-Mediated C-C Bond Cleavage [J]. Advanced Synthesis Catalysis, 2018,361(18):3601-3606 [5] Elizabeth M. Dauncey, Sara P. Morcillo. Photoinduced Remote Functionalizations via Iminyl Radical-Promoted C#8211;C and C#8211;H Bond Cleavage Cascades [J]. Angew. Chem. Int. Ed., 2017,57(3):744-748 [6] Xinxin Wu, Chen Zhu. Recent Advances in Ring-Opening Functionalization of Cycloalkanols by C#8211;C σ-Bond Cleavage [J]. Chem. Rec., 2018, 18: 1#8211;13 [7] Kunfang Jia, Yiyun Chen. Visible-light-induced alkoxyl radical generation for inert chemical bond cleavage/functionalization [J]. Chem.Commun.,2018,54: 6105#8212;6112 [8] Xuan Zhou, Guangbin Dong. (4 1) vs (4 2): Catalytic Intramolecular Coupling between Cyclobutanones and Trisubstituted Allenes via C-C Activation [J]. J. Am. Chem. Soc.,2015, 137(42): 13715-13721

3. 毕业设计（论文）进程安排

2018.12.2-12.21 下达任务，提出要求，开始查阅文献 2018.12.22-2019.1.18 查阅文献，完成开题报告 2019.3.2-3.10 设计实验方案，准备实验材料 2019.3.11-5.15 完成毕业论文实验部分 2019.5.16-6.7 毕业论文的撰写、修改、成文装订 2019.6.8-6.14 论文答辩