1. 毕业设计（论文）的内容和要求

油酸酯是一种无色透明、具有一定气味的粘稠状液体，它们在工业上被广泛应用生物柴油及润滑油。

工业上制备油酸酯多是以浓硫酸作催化剂，用油酸与各种醇为原料进行酯化反应而得，该催化剂会腐蚀设备，本实验自制C/Si固体酸催化来催化酯化油酸和醇的反应，不仅解决了设备的腐蚀问题，还为解决酯化催化剂的回收问题提供新的思路。

2. 参考文献

[1] Atadashi I M，Aroua M K，Abdul Aziz A R，et al. Production of biodiesel using high free fatty acid feedstocks[J]. Renewable and Sustainable Energy Reviews,2012,16(5)：3275-3285. [2] Engler C R, Johnson L A, Lepori W A , et al. Effects of processing and chemical characteristics of plant oils on performance of an indirect-injection diesel engine[J]. J Am OilChem Soc,1983, 60(8):1592-1596. [3] Mohamad I, Widyan A, Ghassan T, et al. Uilization of ethyl ester of waste vegetable oils as fuel in diesel engines[J].Fuel Processing Technology,2002,(76):91-103. [4]AMIN T K,NOR A,HOSSEN M.A review on novel processes of biodiesel production from waste cooking oil[J].Applied Energy,2013,104:683-710. [5] Kiss A A,Dimian A C,Rothenberg G. Solid acid catalysts for biodiesel production-towards sustainable energy[J]. Advanced Synthesis and Catalysis, 2006,348(1/2): 75－81. [6] Peters T A, Benes N E, Holmen A, et al. Comparison of commercial solid acid catalysts for the esterification of acetic acid with butanol[J]. Applied Catalysis A: General,2006, 297(2): 182－188. [7]Gong S W,Lu J, Wang H H,et al.Biodiesel production via esterification of oleic acid catalyzed by picolinic acid modified 12-tungstophosphoric acid[J].Applied Energy,2014,134:283-289. [8]Wang L T, Dong X Q,Jiang H E, et al.Orderedmesoporous carbon supported ferric sulfate:A novel catalyst for the esterification of free fatty acids in waste cooking oil[J].Fuel Processing Technolodgy,2014,128:10-16. [9]Zabeti M,Wan Daud W M A,Aroua M K. Activity of solid catalysts for biodiesel production：A review[J].Fuel Processing Technology,2009,90(6):770-777. [10] Surbhi S,Arora A K,Badoni R P,et al. Biodiesel production using heterogeneous catalysts[J]. Bioresource Technology,2011,102(3):2151-2161. [11]Geng L,Yu G,Wang Y,et al.[J].Applied Catalysis A:General,2012,427-428:137-144. [12]Guo F,Xiu Z L,Liang Z X.[J].Applied Energy,2012,98:47-52. [13] Toda M,Takagaki A,Okamura M,et al. Biodiesel made with sugar catalyst[J]. Natural,2005, 438(10): 178－179. [14] Lou W Y,Zong M H,Duan Z Q.Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts[J].Bioresource Technology, 2008, 99(18): 8752－8758. [15] 王督,苏有勇,王华等.碳基固体酸催化高酸值生物柴油原料降酸效果[J].农业工程学报,2009,25(11):274-277. [16]Li M,Zheng Y,Chen Y,et al.[J].Bioresource Technology,2014,154:345-348.

3. 毕业设计（论文）进程安排

2017.12.23-2017.12.30确定课题，查阅文献 填写进程表 2018.1.3-2018.1.17 撰写开题报告并翻译外文文献 填写进程表 2018.2.24-2018.4.30 ` 研究设计实验方案，熟悉实验细节建立相关化合物的定性和定量分析方法并建立实验方法，进行实验填写进程表 2018.5.1-2018.5.20 做课题实验，将数据整理分析，撰写论文， 填写进程表 2018.5.21-2018.5.31 修改并完成论文 填写进程表 2018.6 准备答辩 填写进程表