1. 毕业设计（论文）的内容和要求

苯二酚是重要的化工产品，用途极其广泛.目前制备苯二酚的研究大多集中在由过氧化氢直接氧化苯酚的工艺路线上，该路线流程简单，反应条件温和，过氧化氢价廉，氧化副产物(水)无污染，符合绿色化学的要求，是目前最理想的生产苯二酚的方法.在分子筛及多孔材料中引入金属活性组分，将其用于以双氧水为氧化剂的苯酚经基化反应所涉及的多孔材料种类繁多，如HMS , TS-1 ,MCM-41 , MCM-48 , MOR3等.纳米四元水滑石具有较好的孔道结构，是石油化工领域重要的催化剂，但将其用于以双氧水为氧化剂、水为溶剂的苯酚氧化反应体系的研究较少.本论文以四元纳米水滑石为研究对象，分别采用浸渍法、沉淀法及离子交换法制备了系列催化剂，系统考察了制备方法、活性组分以及助剂等因素对苯酚氧化反应性能的影响.

2. 参考文献

[1] Fu Z H,CHen J H,Yin D L,et a1.Highly effective Cu-HMS catalyst for hydroxylation of phenol [J].fatal Letters, 2000,66:105-108. [2] LeeC W,Ahnn D H ,Wang B,et a1.Hydroxylation fo phenol over surface functionalized MCM-41 supported metal cata-lyst[J].Microporous Mesoporous Materia1s,2001,44-45:587-594. [3] Maurya M R,Salam J J,Chand T S.Liquid-phase catalytic hydroxylation of phenol using Cu(II),Ni(II) and Zn(II) complexes of amidate ligand encapsulated in zeolite-Y as catalysts[J].fatal Letters,2003,89(3-4):219-227. [4] He Ji,XuW P,Evans D G,et al.Role of pore size and surface properties of Ti-MCM-41 catalysts in the hydroxylation of aromatics in the liquid phase[J].Microporous Mesoporous Materia1s,2001,44-45:581-586. [5] Tanev P T,Chbwe M,Pinnavaia T.A new templating route to ordered mesoporous material[J].Nature,1994,368:321. [6] 熊春荣，林衍华，卢文奎.过氧化氢苯酚经基化合成苯二酚的研究进展「J].工业催化，2005,11(4):7-11. [7] Wang J,Park J N,WeX Y,et al.Room-temperature heterogeneous hydroxylation of phenol with hydrogen peroxideover Fe,Co ion-exchanged Na-zeolite[J].Chem Commun,2003(5):628-629. [8] Wang L P, Kong A G , Chen B , et al. Direct Synthesis ,Charac;terization of Cu SBA-15 and Its High Catalytic; Activity in Hydroxylation of Phenol by H2O2 [J] . J Mol Catal A , 2005, 230:143-150. [9] Jiang T L, Tao H X , Ren JW，et al. Fluoride Ions Assistant Synthesis of Extremely Hydrothermal Stable Al-SBA-15 with Controllable Al Content[J].Micropor Mesopor Mater, 2011,142 :341 346. [10] Yin A Y ,Guo X Y , Dai W L，et al. Effect of Si/Al Ratio of Mesoporous Support nn the Structure Evolution and Catalytic Performance of the Cu/Al-HMS Catalyst [J] . J Phys Chem C, 2010, 114:8523-8532. [11] Karakhanov E A, Maximov A L, Kardasheva Y S, et al. Ivanova, E. Lurie-Luke, J.A. Seeiey, S.L. Cron, Ind. Eng. Chem. Res. 49 (2010)4607#8211;4613. [12] He Z, Wu J, Gao B, H. ACS Appl Mater Interfaces 7 (2015) 2424#8211;2432. [13] S. Pithakratanayothin, R. Tongsri, T. Chaisuwan, S. Wongkasemjit, Mater. Chem. Phys. 181 (2016) 452#8211;461. [14] Y.Q. Jiang, K.F. Lin, Y.N. Zhang, J. Liu, G.H. Li, J.M. Sun, X.Z. Xu, Appl. Catal. AGen. 445 (2012) 172#8211;179. [15] T.R. Simmons, G. Berggren, M. Bacchi, M. Fontecave, V. Artero, Coord. Chem. Rev. 270 (2014) 127#8211;150. [16] D. Schilter, J.M. Camara, M.T. Huynh, S. Hammes-Schiffer, T.B. Rauchfuss, Chem. Rev. 116 (2016) 8693#8211;8749. [17] V. Artero, G. Berggren, M. Atta, G. Caserta, S. Roy, L. Pecqueur, M. Fontecave, Acc. Chem. Res. 48 (2015) 2380#8211;2387. [18] R.M. Bullock, M.L. Helm, Acc. Chem. Res. 48 (2015) 2017#8211;2026.

3. 毕业设计（论文）进程安排

2017.12.23-2017.12.30确定课题，查阅文献 填写进程表 2018.1.3-2018.1.18 撰写开题报告并翻译外文文献 填写进程表 2018.2-2018.4 ` 研究设计实验方案，熟悉实验细节建立相关化合物的定性和定量分析方法并建立实验方法，进行实验填写进程表 2018.5.1-2018.5.20 做课题实验，将数据整理分析，撰写论文， 填写进程表 2018.5.21-2018.5.31 修改并完成论文 填写进程表 2018.6 准备答辩填写进程表