1. 毕业设计（论文）的内容和要求

我们选题的意义在于:合成新型无机功能材料,丰富无机一有机杂化硼酸盐的结构化学。

众所周知,硼酸盐化合物具有优良的光学性质,而由于有机组分的掺入,无机#8212;有机杂化硼酸盐还显示出催化、吸附等多方面的性能,因此开展无机一有机杂化硼酸盐的合成研究具有一定的现实意义22。

总之,我们的目的是开发溶剂热合成新路线,设计合成新型无机一有机杂化硼酸盐,探索新的功能材料。

2. 参考文献

[1]刘美辰. 无机#8212;有机杂化硼酸盐的溶剂热合成与表征[D].大连理工大学,2010. [2] Christ C L, Clark J R, et al. A crystal一chemical classification of borate structure with emphasis on hydrated borates [J]. Phy. Chem. Mineral.,1977,2:59一87. [3]陈兴顺. 系列基于硼酸单元的无机和有机硼化物合成与表征[D].安徽工业大学,2013. [4] D.M.S ch u b e r t, M.Z . V is i ,C . B.Knobler. Guanidinium andimidazoliumborates containingthe first examples of anisolatednonaborate oxoanion:[B9O12(OH) 6]3#8211; [J ]. In o r g.Che m.,2 00 0 (3 9) :2 25 0 -2 25 1 . [5]G. M. Wang, Y. Q. Sun, G. Y. Yang. Syntheses and crystal structures of two new organically templated borates. J.Solid.State.Chem. 2004,177, 4648-4654. [6]王国明，杨国昱.[C6N2H16][B4O5(OH)4]:有机胺模板的硼酸盐的水热合成和晶体结构[J].大环化学和超分子化学研究进展，2004(8)：358-359. [7]C.Y.Pan,G.M.Wang,S.T.Zheng,etal.Syntheses,Characterizations,andCrystal Structures of Two New Organically Templated Borates[J].Z.Anorg.Allg.Chem.,2007(633):336-340. [8]C.Y.Pan,G.M.Wang,S.T.Zheng,etal.[NH3CH2CHCH3NH3]][B8O11(OH)4]#183;=H2O:Synthesis and characterization of the first 1D borate templated by 1,2-diaminopropane[J].J.Solid.State.Chem.,2007(180):1553-1558. [9]G.J.Cao, Y.Q.Sun, S.T.Zheng, etal.An Alcohol-templated Borate Based on [B14O20(OH)6]4#8722;Polyborate Anions[J].Chinese.J.Struct.Chem.,2009(28):525-530. [10]S.H.Yang,G.B.Li,S.J.Tian,etal.Synthesis and Structure of [C2H10N2][B5O8(OH)]:A Nonmetal Penta borate with Nonlinear Optical Properties [J].CrystalGrowthDesign,2007(7):1245-1250. [11]S.H.Yang, G.B.Li, S.J.Tian,etal. Synthesis and structure of a 1,6-hexyl diamine heptaborate,[H3N(CH2)6NH3][B7O10(OH)3[J].J.SolidStateChem.,2007(180):2225-2232. [12]H.H.Y.Sung, M.M.Wu, I.D.Williams.A templated borate polymer from boric acid”flux#8217;synthesis:[Cu(en)2][B7O13H3]n [J].Inorg.Chem.Commun.,2000(3):401-404. [13]H.X.Zhang, S.T.Zheng, G.Y.Yang.Pentaethy lenehexamine manganese(II)Pentaborate[J].Acta.Cryst.E.,2004(C60):m241-m243. [14]G.M.Wang,Y.Q.Sun,G.Y.Yang,syntheses and crystalstructures of three new borate stemplated by transition-metalcompound es insitu[J].J.Solid.StateChem.,2006(179):1545-1553. [15]G.M.Wang,Y.Q.Sun,G.Y.Yang.Syntheses and crystal structures of t wo new pentaborates [J].J.Solid.State.Chem.,2005(178):729-735. [16]Z.H.Liu, J.J.Zhang, W.J.Zhang.Synthesis,crystalstructure and vibrational spectroscopy of a n ovel mixed ligands Ni(II)pentaborate:[Ni(C4H10N2)(C2H8N2)2][B5O6(OH)4]2[J].Inorg.Chim.Acta.,2006(359):519-524. [17]C.Y.Pan,S.Hu,D.G.Li.The first ferroelectric templated borate:[Ni(en)2pip][B5O6(OH)4]2 [J].Dalton.Trans.,2010(39):5772-57 [18]Bondareva O S, Simonov M A, Egorov-Tismenko Y K, et al. Crystal structure of LiZn[BO3] and LiMn[BO3] [J].Sov.Phys.Cryst.23(3)(1978)269-271. [19]Legagneur V, An Y,Mosbah A, et al. LiMBO3(M=Mn,Fe,Co):Synthesis, crystal structure and lithium deinsertion /insertion properties[J].Solid State Ionics,2001,139(1-2):37-46. [20] J. B. Goodenough, H. Y. P. Hong, J. A. Kafalas, Fast Na -Ion Transport in Skeleton Structures. Materials Research Bulletin 11,203-220(1976). [21] H. Y. P. Hong, Crystal Structures and Crystal Chemistry in the System Na1 xZr2SixP3#8722;xO12.Materials Research Bulletin 11,173-182(1976). [22]黄广. 水（溶剂）热条件下硼酸盐的探索合成与表征[D].北京理工大学,2015.

3. 毕业设计（论文）进程安排

2018.10-2018.11 查阅文献 熟悉国内外研究现状和进展 2018.11-2018.12 查找原料化合物 确定合成原料，合成路线，测定方法 2019.01-2019.04 实验阶段 合成出新的目标化合物并进行定性测定 2019.05-2019.06 论文阶段 撰写论文 2019.06 毕业论文阶段 完成本科生毕业论文