1. 毕业设计（论文）的内容和要求

本次毕业论文的主要内容是超薄MOF混合基质膜的制备及分离性能研究。

1、理解气体分离的基本概念、原理、实验流程图以及影响性能的主要因素； 2、了解混合基质膜的基本制备方法及其所应用的分离体系； 3、熟悉ZIF-8的常规物化知识； 4、合理安排实验进程，工作时间不迟到早退； 5、实验认真仔细，对实验现象进行详细的记录，定期对实验数据进行总结，及时调整实验方案； 6、工作积极主动，勤于思考，做好实验室安全卫生工作。

2. 参考文献

[1]周胜,侯倩倩,魏嫣莹,等. 金属有机骨架膜的制备与应用进展. 化工进展,2019,38(1):467-484. [2]. Jingtao Wang, Shaofei Wang, Qingping Xin and Yifan Li. Perspectives on water-facilitated CO2 capture materials. J. Mater. Chem. A, 2017,5, 6794. [3]. 陈英波，赵林飞，王彪，胡晓宇，刘冬青，周凤潇，张宇峰. 沸石咪唑骨架材料（ZIF-8）的结构生长过程. 天津工业大学学报, 2016. [4]. Ming Qiu, Chunju He. E#64259;cient removal of heavy metal ions by forward osmosis membrane with a polydopamine modi#64257;ed zeolitic imidazolate framework incorporated selective layer. Journal of Hazardous Materials 367 (2019) 339#8211;347. [5]. Leland M Vane. Review: membrane materials for the removal of water from industrial solvents by pervaporation and vapor permeation. J Chem Technol Biotechnol 2019; 94: 343#8211;365. [6]. Guangwei He, Mostapha Dakhchoune, Jing Zhao, Shiqi Huang, and Kumar Varoon Agrawal. Electrophoretic Nuclei Assembly for Crystallization of High-Performance Membranes on Unmodified Supports. Adv. Funct. Mater. 2018, 28, 1707427. [7]. Guangli Yu, Xiaoqin Zou, Lei Sun, Baisong Liu, Ziyang Wang, Panpan Zhang, and Guangshan Zhu. Constructing Connected Paths between UiO-66 and PIM-1 to Improve Membrane CO2 Separation with Crystal-Like Gas Selectivity. Adv. Mater. 2019, 1806853. [8]. Wei-Jin Li, Min Tu, Rong Cao and Roland A. Fischer. Metal#8211;organic framework thin #64257;lms: electrochemical fabrication techniques and corresponding applications perspectives. J. Mater. Chem. A, 2016,4, 12356. [9]. Chun-sheng Wu, Zhen-hu Xiong, Chen Li and Jin-miao Zhang. Zeolitic imidazolate metal organic framework ZIF-8 with ultra-high adsorption capacity bound tetracycline in aqueous solution. RSC Adv., 2015,5, 82127. [10]. V. I. Isaeva, M. I. Barkova, L. M. Kustov, D. A. Syrtsova, E. A. E#64257;mova and V. V. Teplyakov. In situ synthesis of novel ZIF-8 membranes on polymeric and inorganic supports. J. Mater. Chem. A, 2015,3, 7469. [11]. Qianqian Hou, Ying Wu,Sheng Zhou, Yanying Wei, Jgrgen Caro, and Haihui Wang. Ultra-Tuning of the Aperture Size in Stiffened ZIF-8_Cm Frameworks with Mixed-Linker Strategy for Enhanced CO2/CH4 Separation. Angew .Chem. Int. Ed. 2019, 58,327#8211;331. [12]. Jianfeng Yao, Dehua Dong, Dan Li, Li He, Gengsheng Xu and Huanting Wang. Contra-di#64256;usion synthesis of ZIF-8 #64257;lms on a polymer substrate. Chem. Commun., 2011,47,2559#8211;2561. [13]. Yuan Peng,Yanshuo Li, Yujie Ban, and Weishen Yang. Two-Dimensional Metal#8211;Organic Framework Nanosheets for Membrane-Based Gas Separation. Angew .Chem. Int.Ed. 2017, 56,9757#8211;9761. [14]. R. Adams, C. Carson, J. Ward, Metal organic framework mixed matrix membranes for gas separations. Micropor. Mesopor. Mater., 131 (2010) 13-20. [15]. T. H. Bae, J. S. Lee, W. Qiu. A high-performance gas-separation membrane containing submicrometer-sized meta-organic framework crystals. Angew. Chem. Int. Ed., 49 (2010) 1-5.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 19.2.25~19.4.7 文献调研，开题报告 19.4.8~19.5.26 开展实验工作 19.5.27~19.5.31 中后期实验阶段及数据收集 19.6.1~19.6.9 数据整理，撰写论文