介孔V-Zr的制备及其在萘的液相氧化中的应用任务书
2020-06-26 19:53:23
1. 毕业设计(论文)的内容和要求
1、培养学生巩固和扩展并综合运用所学的基础理论和专业知识,培养学生运用所学知识独立分析、解决实际问题能力; 2、培养学生初步的科研能力、创新意识和创新能力; 3、培养学生自己动手做实验的能力,研究反应条件,分析处理实验结果数据的能力; 4、培养学生正确的研究思想、理论联系实际的工作作风和严肃的科学态度; 5、培养学生与他人协作的能力和刻苦钻研、勇于创新的精神; 6、培养学生进行方案设计、文献资料查阅整理、理论计算、外文资料的阅读和翻译、文字表达等方面的能力和技巧以及提出论点、综合论证、总结写作等基本技能。
2. 参考文献
1. P. Henner, M. Schiavon, J. L. Morel and E. Lichtfouse, Polycyclic Aromatic Hydrocarbon (PAH) Occurrence and Remediation Methods, Anal. Mag., 25 (1997) pp.M56-M59 2. M.S. Callen, M.T. de la Cruz, J.M. Lopez, A.M. Mastral, PAH in airborne particulate matter. Carcinogenic character of PM10 samples and assessment of the energy generation impact, Fuel Process. Technol. 92 (2011) 176#8211;182. 3. Call#233;n M S, De la Cruz M T, L#243;pez J M and Mastral A M 2011 PAH in airborne particulate matter.: carcinogenic character of PM10 samples and assessment of the energy generation impact Fuel Process. Technol. 92 176 4. Koyama J. Anti-infective quinone derivatives of recent patents.[J]. Recent Pat Antiinfect Drug Discov. 2006, 1(1):113-125. 5. Zhang G Y, Long J L, Wang X X, Zhang Z Z, Dai W X, Liu P, Li Z H, Wu L, Fu X Z. Langmuir, 2010, 26: 1362 6. N. Aktas, H. Cicek, A.T. Unal, G. Kibarer, N. Kolankaya, A. Tanyolac, Reaction kinetics for laccase-catalyzed polymerization of 1-naphthol, Bioresource Technol. 80 (2001) 29#8211;36. 7. 8. M. Selvaraj, T.G. Lee, A novel route to produce phthalic anhydride by oxidation of o-xylene with air over mesoporous V-Mo-MCM-41 molecular sieves, Micropor. Mesopor. Mater. 85 (2005) 39#8211;51. 9. Sayil C, Deniz N G, Cinarli A. Synthesis of N-, S-, O-substituted quinone dyes and their dyeability on polyester fibers[J]. Progress in Organic Coatings, 2016, 98:39-42. 10. Chelinho S, Cmn M, Francisco R, et al. Toxicity of the bionematicide 1,4-naphthoquinone on non-target soil organisms.[J]. Chemosphere, 2017, 181:579. 11. Yang S, Jan Y H, Mishin V, et al. Diacetyl/L-xylulose reductase mediates chemical redox cycling in lung epithelial cells[J]. Chemical Research in Toxicology, 2017. 12. Abiko Y, Shinkai Y, Unoki T, et al. Polysulfide Na2S4 regulates the activation of PTEN/Akt/CREB signaling and cytotoxicity mediated by 1,4-naphthoquinone through formation of sulfur adducts[J]. Scientific Reports, 2017, 7(1):4814. 13. Silicon containing catalysts, MARTIN MANFRED, SCHMIDT WALTER,SCHARFE GERHARD [P]. US4111967,1978 - 09 - 05. 14. Preparation of an improved catalyst for the manufacture of naphthoquinone, ISHIBE NOBUYUKI [US],THOMAS RENARD L [US],TASSET EMMETT L [US][P]. US4533653,1985 - 08 - 06. 15. Rosowski F, Altwasser S, Dobner C K, et al. New silver- and vanadium-containing multimetal oxides for oxidation of aromatic hydrocarbons[J]. Catalysis Today, 2010, 157(1#8211;4):339-344. 16. Karam F F, Kadhim M I and Alkaim A F 2015 Optimal conditions for synthesis of 1, 4-naphthaquinone by photocatalytic oxidation of naphthalene in closed system reactor Int. J. Chem. Sci. 13 650 17. H.R. Khavasi, S.S.H. Davarani, N. Safari, Remarkable solvent effect on the yield and specificity of oxidation of naphthalene catalyzed by iron(III)porphyrins, J. Mol. Catal. A 188 (2002) 115#8211;122. 18. S. Shylesh, A.P. Singh, Synthesis, characterization, and catalytic activity of vanadium-incorporated, -grafted, -immobilized mesoporous MCM-41 in the oxidation of aromatics, J. Catal. 228 (2004) 333#8211;346. 19. H.H. Monfared, Z. Amouei, Hydrogen peroxide oxidation of aromatic hydrocarbons by immobilized iron(III), J. Mol. Catal. A 217 (2004) 161#8211;164. 20. Adam F, Andas J, Rahman I A. A study on the oxidation of phenol by heterogeneous iron silica catalyst[J]. Chemical Engineering Journal, 2010, 165(2):658-667. 21. Shylesh S and Singh A P 2004 Synthesis, characterization, and catalytic activity of vanadium-incorporated, -grafted, and -immobilized mesoporous MCM-41 in the oxidation of aromatics J. Catal. 228 333 22. Bang#243; A and Hal#225;sz J 2009 Oxidation of condensed cyclic hydrocarbons with H2O2 in the presence of modified MCM-41 and SBA-15 mesoporous catalysts Reac. Kinet. Mech. Cat. 96 413 23. Andas J, Adam F, Rahman I A and Yun T Y 2014 Optimization and mechanistic study of the liquid-phase oxidation of naphthalene over biomass-derived iron catalyst Chem. Eng. J. 252 382 24. Yang F, Gao S, Xiong C, Wang H, Chen J and Kong Y 2015 Coordination of manganese porphyrins on amino-functionalized MCM-41 for heterogeneous catalysis of naphthalene hydroxylation Chin. J. Catal. 36 1035 25. Morris S M, Fulvio P F and Jaroniec M 2008 Ordered Mesoporous Alumina-Supported Metal Oxides J. Am. Chem. Soc. 130 15210 26. Cai W, Yu J, Anand C, Vinu A and Jaroniec M 2011 Facile Synthesis of Ordered Mesoporous Alumina and Alumina-Supported Metal Oxides with Tailored Adsorption and Framework Properties Chem. Mater. 23 1147 27. Seifvand N, Kowsari E. Synthesis of mesoporous Pd-doped TiO2 templated by a magnetic recyclable ionic liquid for efficient photocatalytic air treatment[J]. Industrial Engineering Chemistry Research, 2016, 55(40). 28. Shyamsundar M, Shamshuddin S Z M, Vasanth V T and Mohankumar T E Simple but efficient synthesis of bis(indolyl)methanes by the condensation reaction of substituted benzaldehydes with indole over mesoporous ZrO 2 #8211;MgO green catalysts under solvent free conditions[J]. Journal of Porous Materials, 2016:1-9. 29. Wu K, Yang M, Pu W, Wu Y, Shi Y and Hu H Carbon Promoted ZrO2 Catalysts for Aqueous-Phase Ketonization of Acetic Acid[J]. Acs Sustainable Chemistry Engineering, 2017, 5(4). 30. Xue M, Yu J, Chen H and Shen J Surface Acidic and Redox Properties of V#8211;Ag#8211;O/TiO 2, Catalysts for the Selective Oxidation of Toluene to Benzaldehyde[J]. Catalysis Letters, 2007, 330(3-4):117-126. 31. Skoda D, Styskalik A, Moravec Z, Bezdicka P and Pinkas J Templated non-hydrolytic synthesis of mesoporous zirconium silicates and their catalytic properties[J]. Journal of Materials Science, 2015, 50(9):3371-3382. 32. Chang Y, Wang C, Liang T, Zhao C, Luo X, Guo T, Gong J and Wu H Sol#8211;gel synthesis of mesoporous spherical zirconia[J]. Rsc Advances, 2015, 5(127):104629-104634. 33. Sobańska K, Pietrzyk P, Sojka Z. Generation of Reactive Oxygen Species via Electroprotic Interaction of H2O2 with ZrO2 Gel: Ionic Sponge Effect and pH-Switchable Peroxidase- and Catalase-Like Activity[J]. Acs Catalysis, 2017, 7(4). 34. Sto#353;i#263; D, Bennici S, Pavlovi#263; V, et al. Tuning the acidity of niobia: Characterization and catalytic activity of Nb2O5#8211;MeO2 (Me = Ti, Zr, Ce) mesoporous mixed oxides[J]. Materials Chemistry Physics, 2014, 146(3):337-345. 35. Li X H, Li W Y and Xie K C 2005 Supported Vanadia Catalysts for Dehydrogenation of Ethylbenzene with CO2 Catal. lett. 105 223 36. Liu J, Zou S, Li S, Liao X, Hong Y, Xiao L and Fan J 2013 A general synthesis of mesoporous metal oxides with well-dispersed metal nanoparticles via a versatile sol-gel process J. Mater. Chem. A 1 4038 37. Yang P, Zhao D, Margolese D I, Chmelka B F and Stucky G D 1999 Block Copolymer Templating Syntheses of Mesoporous Metal Oxides with Large Ordering Lengths and Semicrystalline Framework Chem. Mater. 11 2813 38. Fang H, Wan T, Shi W and Zhang M Design and synthesis of large-pore p 6 mm, mesoporus zirconia thin films templated by a novel block copolymer[J]. Journal of Non-Crystalline Solids, 2007, 353(16#8211;17):1657-1661. 39. Das S K, Bhunia M K, Sinha A K and Bhaumik A Self-Assembled Mesoporous Zirconia and Sulfated Zirconia Nanoparticles Synthesized by Triblock Copolymer as Template[J]. J.phys.chem.c, 2009, 113(20):8918-8923. 40. Miao Z, Zhao H, Yang J, Zhao J, Song H and Chou L Mesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application.[J]. Dalton Transactions, 2015, 44(7):2997. 41. Riemer T, Spielbauer D, Hunger M, Mekhemer G A H and Knozinger H Super Acid Properties of Sulfated Zirconia as Measured by Raman and 1H MAS NMR Spectroscopy[J]. Journal of the Chemical Society Chemical Communications, 1994, 10(10):1181-1182. 42. Florea M, Marin R S, P#259;l#259;#351;anu F M, Nea#355;u F and Pacirc;rvulescu V I Mesostructured vanadia#8211;alumina catalysts for the synthesis of vitamin K3[J]. Catalysis Today, 2015, 254:29-35.
3. 毕业设计(论文)进程安排
2018年2月-3月:查找相关文献,熟悉课题研究背景,并完成一 篇外文翻译。
2018年3月-4月:完成开题报告,制定实验计划。
2018年4月-5月:进行实验得出数据。
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