复合型离子液体支撑液膜的二氧化碳分离性能强化任务书
2020-06-24 19:46:39
1. 毕业设计(论文)的内容和要求
随着化石燃料的使用,全球升温、冰川融化、海平面上升等环境问题日益突出,二氧化碳分离技术也因此得到发展。
膜分离技术相较于其他成熟工艺而言,具有低过程成本、小单元规模、简单操作等优点备受关注。
而离子液体作为一种新兴的二氧化碳吸附剂,凭借其极低饱和蒸气压、不可燃性、高稳定性和低能耗,成为研究热点。
2. 参考文献
1. Jacobson M Z. Review of solutions to global warming, air pollution, and energy security. Energy Environmental Science, 2009, 2(13):148-173. 2. Dai Z, Noble R D, Gin D L, et al. Combination of ionic liquids with membrane technology: A new approach for CO2, separation. Journal of Membrane Science, 2016, 497:1-20. 3. Bates E D, Mayton R D, Ioanna Ntai A, et al. CO2 Capture by a Task-Specific Ionic Liquid. Journal of the American Chemical Society, 2002, 124(6):926-7. 4. Mahurin S, Hillesheim P, Yeary J, et al. High CO2 solubility, permeability and selectivity in ionic liquids with the tetracyanoborate anion. Rsc Advances, 2012, 2(31):11813-11819. 5. Neves L A, Crespo J G, Coelhoso I M. Gas permeation studies in supported ionic liquid membranes. Journal of Membrane Science, 2010, 357(1#8211;2):160-170. 6. Shan W, Hopkinson D, Myers C, et al. Mechanically robust hollow fiber supported ionic liquid membranes for CO2, separation applications. Journal of Membrane Science, 2014, 470(23):52-59. 7. Albo J, Tsuru T. Thin Ionic Liquid Membranes Based on Inorganic Supports with Different Pore Sizes. Industrial Engineering Chemistry Research, 2014, 53(19):8045-8056. 8. Kasahara S, Kamio E, Ishigami T, et al. Amino acid ionic liquid-based facilitated transport membranes for CO2 separation. Chemical Communications, 2012, 48(55):6903-5. 9. Huang K, Zhang X M, Li Y X, et al. Facilitated separation of CO2, and SO2, through supported liquid membranes using carboxylate-based ionic liquids. Journal of Membrane Science, 2014, 471(6):227-236. 10. Shi W, Myers C R, Luebke D R, et al. Theoretical and experimental studies of CO2 and H2 separation using the 1-ethyl-3-methylimidazolium acetate ([emim][CH3COO]) ionic liquid. Journal of Physical Chemistry B, 2012, 116(1):283-95. 11. Myers C, Pennline H, Luebke D, et al. High temperature separation of carbon dioxide/hydrogen mixtures using facilitated supported ionic liquid membranes . Journal of Membrane Science, 2008, 322(1):28-31. 12. Xie W, Ji X, Xin F, et al. Mass-transfer rate enhancement for CO2, separation by ionic liquids: Theoretical study on the mechanism. AICHE Journal, 2015, 55(1). 13.Ban, Y., et al., Confinement of Ionic Liquids in Nanocages: Tailoring the Molecular Sieving Properties of ZIF-8 for Membrane-Based CO2 Capture. Angew Chem Int Ed Engl, 2015. 54(51): p. 15483-7. 14. Yuan, J., D. Mecerreyes, and M. Antonietti, Poly(ionic liquid)s: An update. Progress in Polymer Science, 2013. 38(7): p. 1009-1036. 15. Scovazzo, P., Determination of the upper limits, benchmarks, and critical properties for gas separations using stabilized room temperature ionic liquid membranes (SILMs) for the purpose of guiding future research. Journal of Membrane Science, 2009. 343(1#8211;2): p. 199-211. 16. Albo, J., T. Yoshioka, and T. Tsuru, Porous Al2O3/TiO2 tubes in combination with 1-ethyl-3-methylimidazolium acetate ionic liquid for CO2/N2 separation. Separation Purification Technology, 2013. 122(3): p. 440#8211;448.
3. 毕业设计(论文)进程安排
3月上旬 熟悉课题,查阅文献,写开题报告,并购买实验药品和玻璃仪器。
3月中旬 熟悉实验装置,在研究生指导下进行离子液体制备实验及膜分离实验初步熟悉。
3月下旬-4月底 独立实验,制备不同离子液体并进行不同比例的混合,进行实验的前期准备。
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