1. 毕业设计（论文）的内容和要求

1、内容： 固体氧化物燃料电池(sofc)因其高效率、无污染、全固态结构和对多种燃料气体的广泛适应性等，有着广阔的市场前景。

传统的金属陶瓷基阳极材料虽然在使用氢气燃料时性能优异，但在使用碳氢燃料时会出现严重的积碳问题。

钙钛矿阳极可以克服碳沉积、镍烧结及硫中毒等金属陶瓷阳极的系列问题。

2. 参考文献

[1] B.C.H. Steele, A. Heinzel. Materials for fuel-cell technologies. Nature, 414 (2001), pp. 345-352 [2] B.C.H. Steele. Fuel-cell technology: running on natural gas. Nature, 400 (1999), pp. 619-621 [3] S. Park, J.M. Vohs, R.J. Gorte. Direct oxidation of hydrocarbons in a solid-oxide fuel cell. Nature, 404 (2000), pp. 265-267 [4] E.P. Murray, T. Tsai, S.A. Barnett. A direct-methane fuel cell with a ceria-based anode. Nature, 400 (1999), pp. 649-651 [5] V. Lawlor, S. Griesser, G. Buchinger, A.G. Olabi, S. Cordiner, D. Meissner. Review of the micro-tubular solid oxide fuel cell (Part I. Stack design issues and research activities). J. Power Sources, 193 (2009), pp. 387-399 [6] Y. Bai, J. Liu, H. Gao, C. Jin. Dip coating technique in fabrication of cone-shaped anode-supported solid oxide fuel cells. J. Alloys Compd., 480 (2009), pp. 554-557 [7] Z.Y. Han, Y.H. Wang, Z.B. Yang, M.F. Han. Electrochemical properties of tubular SOFC based on a porous ceramic support fabricated by phase-inversion method. J. Mater. Sci. Technol., 32 (2016), pp. 681-686 [8] Z.Y. Han, Z.B. Yang, M.F. Han. Fabrication of metal-supported tubular solid oxide fuel cell by phase-inversion method and in situ reduction. Int. J. Hydrogen Energy, 41 (2016), pp. 10935-10941 [9] J. Ding, J. Liu, G.Q. Yin. Fabrication and characterization of low-temperature SOFC stack based on GDC electrolyte membrane. J. Membr. Sci., 371 (2011), pp. 219-225 [10] J.D. Nicholas, L.C. De Jonghe. Prediction and evaluation of sintering aids for cerium gadolinium oxide. Solid State Ionics, 178 (2007), pp. 1187-1194 [11] S.H. Park, H.I. Yoo. Defect-chemical role of Mn in Gd-doped CeO2. Solid State Ionics, 176 (2005), pp. 1485-1490 [12] D.P. Fagg, J.C.C. Abrantes, D. P#233;rez-Coll, P. N#250;#241;ez, V.V. Kharton, J.R. Frade. The effect of cobalt oxide sintering aid on electronic transport in Ce0.80Gd0.20O2#8722;δ electrolyte. Electrochim. Acta, 48 (2003), pp. 1023-1029 [13] T.S. Zhang, J. Ma, L.B. Kong, S.H. Chan, P. Hing, J.A. Kilner. Iron oxide as an effective sintering aid and a grain boundary scavenger for ceria-based electrolytes. Solid State Ionics, 167 (2004), pp. 203-207 [14] V. Gil, J. Tartaj, C. Moure, P. Dur#225;n. Sintering, microstructural development, and electrical properties of gadolinia-doped ceria electrolyte with bismuth oxide as a sintering aid. J. Eur. Ceram. Soc., 26 (2006), pp. 3161-3171 [15] Z. Liu, Z. Lei, S.D. Song, L. Yu, M.F. Han. Doped zirconia/ceria electrolyte fabricated at low temperature. Prog. Chem., 23 (2011), pp. 470-476

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2月25日 ~3月3日 确定课题，布置任务，阅读文献资料，并进一步检索文献。

3月4日 ~3月17日 翻译英文文献，完成开题报告；制订实验计划，了解实验仪器设备及实验方法。

3月18日 ~ 3月24日 修改开题报告及英文文献翻译，进行开题，根据意见完善实验计划。