炭黑改性双连续PP/SBS共混物的制备及其导电性能研究任务书
2020-05-01 08:47:27
1. 毕业设计(论文)的内容和要求
采用双辊开炼的方法制备具有不同cb含量和cb在不同组分的pp/sbs/炭黑共混物。
首先,在聚丙烯(pp)中加入不同量的炭黑(cb)制备不同cb含量的pp,研究不同cb含量对pp力学性能和导电性能的影响;其次,制备具有不同cb含量的苯乙烯-丁二烯-苯乙烯嵌段共聚物(sbs),研究不同cb含量对sbs力学性能和导电性能的影响;最后,分别先在pp中加入cb再和sbs共混,先在sbs中加入cb再和pp共混,先pp和sbs共混再加入cb,制备cb在不同组分中的pp/sbs共混材料,研究cb在不同组分中对共混物的力学性能、导电性能的影响,并提出导电机理。
实验采用模压法制备样品,并借助电子万能试验机、高阻计、扫描电子显微镜(sem)、傅里叶变换红外光谱仪(ftir)等,分析制备共混物的力学性能、导电性能、相容性等。
2. 参考文献
[1]. Wang P, Zhang J. A novel combination of sandwich and co-continuous structure based on polypropylene and styrene-butadiene-styrene block copolymer formed with wide range of polypropylene content[J]. Journal of Applied Polymer Science, 2018, 135(4658032). [2]. Du J, Zhao L, Zeng Y, et al. Comparison of electrical properties between multi-walled carbon nanotube and graphene nanosheet/high density polyethylene composites with a segregated network structure[J]. Carbon, 2011, 49(4):1094-1100. [3]. Pang H, Xu L, Yan D X, et al. Conductive polymer composites with segregated structures[J]. Progress in Polymer Science, 2014, 39(11):1908-1933. [4]. Yang H, Gong J, Wen X, et al. Effect of carbon black on improving thermal stability, flame retardancy and electrical conductivity of polypropylene/carbon fiber composites[J]. Composites Science and Technology, 2015, 113:31-37. [5]. Azizi S, David E, Frechette M F, et al. Electrical and thermal phenomena in low-density polyethylene/carbon black composites near the percolation threshold[J]. Journal of Applied Polymer Science, 2019, 136(6):47043. [6]. Pan Y, Liu X, Hao X, et al. Enhancing the electrical conductivity of carbon black-filled immiscible polymer blends by tuning the morphology[J]. European Polymer Journal, 2016, 78:106-115. [7]. Yurddaskal M, Doluel E C, Kartal U, et al. Graphene and carbon black filled conductive nanocomposite films for heating element applications[J]. Journal of Materials Science: Materials in Electronics, 2018, 29(22): 19005-19012. [8]. Su J, Zhang J. Improvement of electrical properties and thermal conductivity of ethylene propylene diene monomer (EPDM)/barium titanate (BaTiO3) by carbon blacks and carbon fibers[J]. Journal of Materials Science: Materials in Electronics, 2017, 28(7):5250-5261. [9]. Yui H, Wu G Z, Sano H, et al. Morphology and electrical conductivity of injection-molded polypropylene/carbon black composites with addition of high-density polyethylene[J]. Polymer, 2006, 47(10):3599-3608. [10]. Wu, D, Lv Q, Feng S, et al. Polylactide composite foams containing carbon nanotubes and carbon black: Synergistic effect of filler on electrical conductivity[J]. Carbon, 2015, 95:380-387. [11]. Zhang Y, Heo Y J, Son Y R, et al. Recent advanced thermal interfacial materials: A review of conducting mechanisms and parameters of carbon materials[J]. Carbon, 2019, 142:445-460. [12]. Song Y, Xu C, Zheng Q. Styrene-butadiene-styrene copolymer compatibilized carbon black/polypropylene/polystyrene composites with tunable morphology,electrical conduction and rheological stabilities[J]. Soft Matter, 2014, 10:2685-2692. [13]. Shen L, Wang F, Yang H, et al. The combined effects of carbon black and carbon fiber on the electrical properties of composites based on polyethylene or polyethylene/polypropylene blend[J]. Polymer Testing, 2011, 30(4):442-448. [14]. 苏珺. 聚烯烃/钛酸钡功能复合材料的制备与性能研究[D], 2017, 南京工业大学. [15]. 陶慧, 陈双俊, 张军. 碳纤维的表面改性对导热顺丁橡胶性能的影响[J]. 弹性体, 2012. 22(3): 第37-42页. [16]. 陶慧, 陈双俊, 张军. 碳纤维对顺丁橡胶导热性能的影响[J]. 橡胶工业, 2012. 59(5): 第265-269页.
3. 毕业设计(论文)进程安排
2.26-3.11 文献查询及文献翻译 3.12-3.18 完成开题报告 3.19-4.22 实验工作 4.23-4.29 论文中期检查 4.30-6.10 进行实验并撰写论文 6.11-6.22 论文答辩
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