1. 毕业设计（论文）的内容和要求

主要内容包括： 通过共醇解方法制备出不同含量的二氧化钛和二氧化硅纳米杂化物。

通过红外和xrd检测产物的晶型和结构，并通过电镜表征粒径，使用这些杂化物研究醇与酸的酯化反应，研究成分与粒径不同对酯化率的影响，从而归纳出纳米颗粒催化剂对酯化反应的影响规律。

具体分为： 第一周～第二周：文献查阅 查阅有关纳米二氧化钛及其掺混物方面的文献，要求学习并掌握利用中国期刊网、ca、ei、elsevier等查阅文献，不少于30篇。

2. 参考文献

[1] C.A. Huerta Aguilar. Oxidation-of-phenols-by-TiO2Fe3O4M-M-Ag-or-Au-hybrid-composites-under-visible-light.Separation and Purification Technology 149 (2015) 265#8211;278 . [2] Ci Zhang Wen.Synthesis of high-reactive facets dominated anataseTiO 2.Journal of Materials Chemistry,0959-9428(2011)2120;1-N. [3] Coumarin-sulfonates-As-potential-leads-for-ROS-inhibition_Bioorganic Chemistry 69 (2016) 37#8211;47. [4]D.Chakraborty.Characterization-of-nonOhmic-electrical-transport-in-double-perovskite-compounds-through-bias-scale-and-nonlinearity-exponent_Journal of Physics and Chemistry of Solids 100 (2017) 19#8211;24 . [5]Fabrication-and-evaluation-of-dual-function-PMMA-nano-carbon-composite-particles-for-UV-curable-anti-glare-coating_Progress in Organic Coatings 101 (2016) 81#8211;89. [6] Giulia Gheno.Accelerated-weathering-degradation-behaviour-of-polyester-thermosetting-powder-coatings_Progress in Organic Coatings 101 (2016) 90#8211;99 . [7] Jianqi Ma.A-mild-synthetic-route-to-Fe3O4-TiO2-Au-composites-preparation-characterization-and-photocatalytic-activity_Applied Surface Science 353 (2015) 1117#8211;1125. [8] JinguoWang.Ordered mesoporous TiO 2 with exposed (001) facets and enhanced activity in photocatalytic selective oxidation of alcohols#8224;. J. Mater. Chem. A, 2013, 1, 1296. [9] Jun-Bing Fan.Controlled Synthesis and Ti#8212;O Bond Stability of Star-Shaped Biodegradable Polyesters via Titanate-Initiated ROP of Cyclic Esters at Ambient Temperature.Macromol. Chem. Phys. 2012, 213, 1499#8722;1508. [10] Laila Galeano.Preparaci#243;n de Sistemas#243;xido de Titanio#243;xido de Silicio (TiO 2 SiO 2 ) mediante el M#233;todoSolvot#233;rmico para AplicacionesenFotocat#225;lisis.Informaci#243;nTecnol#243;gica,Vol. 24(5), 81-92 (2013). [11] Lichao Tan.Synthesis-of-Fe3O4-TiO2-core-shell-magnetic-composites-for-highly-efficient-sorption-of-uranium-VI-.Colloids and Surfaces A Physicochem. Eng. Aspects 469 (2015) 279#8211;286. [12] Pranali P. Chiplunkar, Amit P.Utilization-of-sunflower-acid-oil-for-synthesis-of-alkyd-resin.Progress in Organic Coatings 93 (2016) 61#8211;67. [13] Pravin G. Ingole.Synthesis and characterization of polyamidepolyester thin-film nanocomposite membranes achieved by functionalized TiO 2 nanoparticles for water vapor separation#8224;. J. Mater. Chem. A, 2016, 4. [14] RuhuaZha.Morphology engineering of nanostructured TiO 2 paaticles.Published on 17 December 2014. RSC Adv., 2015, 5, 6481. [15] Tina Harifi, Majid Montazer.A robust super-paramagnetic TiO 2 Fe 3 O 4 Ag nanocomposite with enhanced photo and bio activities on polyester fabric via one step sonosynthesis.UltrasonicsSonochemistry 27 (2015) 543#8211;551. [16] V. Jandov#225;.Infrared laser radiation-produced TiO-doped SiSiO x SiO 2 nanocomposite#8212;Entry to TiO-containing materials.Journal of Photochemistry and Photobiology A Chemistry 332 (2017) 376#8211;383. [17] Wee-Jun Ong.Highly reactive {001} facets of TiO 2 -based composites synthesis, formation mechanism and characterization.Nanoscale, 2014, 6, 1946. [18] Yan Zheng.Growth and photocatalytic performance of carambola-like TiO 2 consisting of nanosheets exposed {001} facets. RSC Adv., 2016, 6, 15485. [19] Yannick Simonin.Zika-Virus-Strains-Potentially-Display-Different-Infectious-Profiles-in-Human-Neural-Cells.EBioMedicine 12 (2016) 161#8211;169. [20] 崔义慧.TiO 2 光催化剂制备及其催化性能研究.辽宁化工,2015,44(11):1285-1287. [21] 董睿.纳米二氧化钛粉体及薄膜制备的研究进展.聚酯工业,2013,26(4):637-640. [22] 李静.纳米二氧化钛复合凹土催化剂的制备和催化聚酯反应.精细化工，2012,29（12）：1190-1194. [23] 王全杰.纳米二氧化钛对聚碳酸酯型聚氨酯黄变性的影响.中国皮革,2009,38(9):15-19. [24] 肖刚.钛系催化剂在聚酯行业应用现状及发展.聚酯工业,2016,29(2):1-4. [25] 苑娜娟.钛系聚酯催化剂的工业应用进展.广州化工,2015,43(13):30-31. [26] 章瑛虹.钛系聚酯催化剂催化活性的影响因素研究.合成纤维工业, 2012,35(4):8-11. [27] 赵学国.醇解法合成锥形氧化锌纳米粉体.硅酸盐学报,2009,37(4):596-600. [28] 周美进.锑钛复合催化剂半消光聚酯等温结晶性能研究.合成纤维工业, 2016,39(1):23-26. [29] 朱雪峰.纳米二氧化钛聚酯催化剂的研究进展.聚酯工业,2013,26(4):5-7.

3. 毕业设计（论文）进程安排

17. 2.22-17. 2.28 文献查阅，了解课题 17. 2.29-17.3.13 英文文献翻译以及完成开题报告 17.3.14-17.4.1 按照实验计划进行试验 17.4.2-17.4.4 清明节休假 17.4.5-17.4.27 按照实验计划进行试验 17.4.28-17.4.30 进行中期检查 17.5.1-17.5.3 劳动节休假 17.5.4-17.5.31 进行实验并整理数据 17.6.1-17.6.14 撰写完成毕业论文 17.6.15-17.6.21 毕业论文答辩