1. 毕业设计（论文）的内容和要求

本课题要求通过查阅相关文献，基于锂硫电池泡沫镍集流体进行改性从而提高电池的综合电化学性能：

2. 参考文献

[1] 陈雨晴,杨晓飞,于滢,等.锂硫电池关键材料与技术的研究进展[J].储能科学与技术，2017, (2). [2] 徐学笛.化学电源的发展及展望[J].化学工程与装备, 2008, (2). [3] Mikhaylik Y, Kovalev I, Schock R, et al. High energy rechargeable Li-S cells for EV application. status, remaining problems and solutions [J]. Ecs Transactions, 2010, 25(35): 23-34. [4] Chen L, Shaw L L. Recent advances in lithium-sulfur batteries [J] . Journal of Power Sources, 2014, 267: 770-783. [5] Yuriy V, Mikhaylik, Akridge J R. Polysulfide shuttle study in the Li-S battery system [J] . J. Electrochem. Soc., 2004, 151(11): A1969-A1976. [6] Xu K. Electrolytes and interphases in Li-ion batteries and beyond [J]. Chemical Reviews, 2014, 114(23): 11503-11618. [7] Zhang S, Ueno K, Dokko K, et al. Recent advances in electrolytes for lithium-sulfur batteries [J]. Advanced Energy Material, 2015, 5(16): doi: 10.1002/aenm.201500117. [8] Scheers J, Fantini S, Johansson P. A review of electrolytes for lithium-sulphur batteries [J]. Journal of Power Sources, 2014, 255: 204-218. [9] Bruce P G, Freunberger S A, Hardwick L J, et al. LiO2 and LiS batteries with high energy storage [J]. Nature Materials, 2012, 11(1):19-29 [10] Xiong S, Xie K, Diao Y, et al. Properties of surface film on lithium anode with LiNO3 as lithium salt in electrolyte solution for lithium-sulfur batteries [J]. Electrochimica Acta, 2012, 83: 78-86. [11] 蔡锐,王月芳,邵宗平. LiFePO4锂电池正极材料的共碳包覆和Mn掺杂的改性[J].南京工业大学学报(自然科学版),2012, (6). [12] Suo L, Hu Y S, Li H, et al. A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries [J]. Nature Communications, 2013, 4: 1481. [13] Zhang S S, Tran D T. How a gel polymer electrolyte affects performance of lithium/sulfur batteries [J]. Electrochimica Acta, 2013, 114: 296-302. [14] Ma G, Wen Z, Wu M, et al. A lithium anode protection guided highly-stable lithium-sulfur battery [J]. Chemical Communications, 2014, 50(91): 14209-14212. [15] 程新兵，张强.金属锂枝晶生长机制及抑制方法[J].化学进展, 2018, (1). [16] 高申，龙泽，高诠,等.TiO2改性层参数对高比能锂硫电池负极材料耐腐蚀性能的影响[J]. 铸造技术, 2015, (7). [17] 袁华栋,罗剑敏,金成滨,等.高性能锂硫电池正极用碳基材料的界面修饰[J].储能科学与技术, 2017, (3). [18] Zheng G, Lee S W, Liang Z, et al. Interconnected hollow carbon nanospheres for stable lithium metal anodes [J]. Nature Nanotechnology, 2014, 9(8): 618-623. [19] Miao Lixiao. Sulfur/carbon composite cathode with net-work for lithium sulfur battery research [D]. Beijing: Beijing Institute of Technology, 2014.

3. 毕业设计（论文）进程安排

第1-2周 阅读一些相关文献,了解课题的背景 第3-7周 制备泡沫镍集流体 第8-10周 通过电化学置换反应对泡沫镍集流体进行改性 第11-13周 组装电池，进行电化学测试 第14-17周 完成毕业论文