1. 毕业设计（论文）的内容和要求

1. 主要研究内容 （1）通过文献调研，了解高抗冲聚苯乙烯复合材料的研究现状，确定高抗冲聚苯乙烯阻燃添加剂的填料配比。

（2）通过实验研究，获得不同填料配比的高抗冲聚苯乙烯复合材料的极限氧指数、垂直燃烧等级、熔融滴落情况和点燃时间等参数。

（3）通过对实验数据进行研究和分析，揭示高抗冲聚苯乙烯复合材料的阻燃性能随填料配比的变化规律。

2. 参考文献

[1] J.谢尔斯, D.B.普里迪. 现代苯乙烯系聚合物[M]. 化学工业出版社材料科学与工程出版中心, 2004. [2] 单雪影. 聚乳酸/含镍化合物纳米复合材料的制备、热性能与阻燃性能研究[D]. 中国科学技术大学, 2014. [3] 杨荣杰, 王建祺. 聚合物纳米复合物加工、热行为与阻燃性能[M]. 北京：科学出版社, 2010. [4] 彭治汉. 聚合物阻燃新技术[M]. 北京：化学工业出版社, 2015. [5] Bourbigot S, Duquesne S. Fire retardant polymers: recent developments and opportunities[J]. Journal of Materials Chemistry, 2007, 17(22):2283-2300. [6] Zaikov G E, Lomakin S M. Ecological issue of polymer flame retardancy[J]. Journal of Applied Polymer Science, 2002, 86(10):14. [7] Wang D, Echols K, Wilkie C A. Cone calorimetric and thermogravimetric analysis evaluation of halogen‐containing polymer nanocomposites[J]. Fire Materials, 2010, 29(5):283-294. [8] Arimitsu U, Masaya K, Yoshitsugu K, et al. Swelling behavior of montmorillonite cation exchanged for ω-amino acids by -caprolactam[J]. Journal of Materials Research, 1993, 8(5):5. [9] Peeterbroeck S, Laoutid F, Taulemesse J M, et al. Mechanical properties and flame‐retardant behavior of ethylene vinyl acetate/high‐density polyethylene coated carbon nanotube nanocomposites[J]. Advanced Functional Materials, 2010, 17(15):2787-2791. [10] Yuan B, Bao C, Song L, et al. Preparation of functionalized graphene oxide/polypropylene nanocomposite with significantly improved thermal stability and studies on the crystallization behavior and mechanical properties[J]. Chemical Engineering Journal, 2014, 237(5):411-420. [11] Jin Z, Pramoda K P, Xu G, et al. Dynamic mechanical behavior of melt-processed multi-walled carbon nanotube/poly(methyl methacrylate) composites[J]. Chemical Physics Letters, 2001, 337(1):43-47. [12] Cipiriano B H, Kashiwagi T, Raghavan S R, et al. Effects of aspect ratio of MWNT on the flammability properties of polymer nanocomposites [J]. Polymer, 2007, 48(20):6086-6096. [13] 柯扬船. 聚合物纳米复合材料[M]. 北京：科学出版社, 2009. [14] Du F, Scogna R C, Zhou W, et al. Nanotube networks in polymer nanocomposites: rheology and electrical conductivity[J]. Macromolecules, 2004, 37(24):9048-9055. [15] Cho T H, Tanaka M, Onishi H, et al. Battery performances and thermal stability of polyacrylonitrile nano-fiber-based nonwoven separators for Li-ion battery[J]. Journal of Power Sources, 2008, 181(1):155-160. [16] Guo B, Jia D, Cai C. Effects of organo-montmorillonite dispersion on thermal stability of epoxy resin nanocomposites[J]. European Polymer Journal, 2004, 40(8):1743-1748. [17] Yong T, Yuan H, Lei S, et al. Preparation and thermal stability of polypropylene/montmorillonite nanocomposites[J]. Polymer Degradation Stability, 2016, 82(1):127-131. [18] Morgan A B, Wilkie C A. 阻燃聚合物纳米复合材料[M]. 国防工业出版社, 2011. [19] 尹昌宇. 三嗪成炭剂的合成及其与聚磷酸铵协同阻燃聚丙烯的研究[D]. 华南理工大学, 2012. [20] Kashiwagi T, Grulke E, Hilding J, et al. Thermal and flammability properties of polypropylene/carbon nanotubes nancomposites[J]. Polymer, 2004, 45:4227-4329. [21] Kashiwagi T, Grulke E, Hilding J, et al. Relation between the viscoelastic and flammability properties of polymer nanocomposites[J]. Polymer, 2008, 49(20):4358-4368. [22] Costachc M C，Heidecker M J，Manias E，et al. The influence of carbon nanotubes, organically modified montmorillonites and layered double hydroxides on the thermal degradation and fire retardancy of polyethylene, ethyleneevinyl acetate copolymer and polystyrene[J]. Polymer, 2007, 48:6532-6545. [23] Schartel B, Braun U. Comprehensive fire behaviour assessment of polymeric materials based on cone calorimeter investigations[J]. e-Polymers, 2003, 3(1):177-190. [24] Liu J, Yu Z, Chang H, et al. Thermal degradation behavior and fire performance of halogen-free flame-retardant high impact polystyrene containing magnesium hydroxide and microencapsulated red phosphorus[J]. Polymer Degradation Stability, 2014, 103(1):83-95. [25] Liu J, Yu Z, Shi Y, et al. A preliminary study on the thermal degradation behavior and flame retardancy of high impact polystyrene/magnesium hydroxide/microencapsulated red phosphorus composite with a gradient structure[J]. Polymer Degradation Stability, 2014, 105(1):21-30. [26] Liu J, Peng S, Zhang Y, et al. Influence of microencapsulated red phosphorus on the flame retardancy of high impact polystyrene/magnesium hydroxide composite and its mode of action[J]. Polymer Degradation Stability, 2015, 121:208-221. [27] Yu Z, Liu J, Zhang Y, et al. Thermo-oxidative degradation behavior and fire performance of high impact polystyrene/magnesium hydroxide/microencapsulated red phosphorus composite with an alternating layered structure[J]. Polymer Degradation Stability, 2015, 115:54-62. [28] Bourbigot S, Duquesne S, Fontaine G, et al. Characterization and reaction to fire of polymer nanocomposites with and without conventional flame retardants[J]. Molecular Crystals and Liquid Crystals, 2008, 486(1):325/[1367]-339/[1381]. [29] Huang G, Wang S, Song P, et al. Combination effect of carbon nanotubes with graphene on intumescent flame -retardant polypropylene nanocomposites [J]. Composites Part A, 2014, 59(2):18-25.

3. 毕业设计（论文）进程安排

1.13～1.23 查阅与论文有关的中英文资料，全面了解课题，把握课题内容，完成开题报告初稿 2.25～3.15 整理筛选资料，详细阅读相关文献，构思论文的框架结构，完成绪论 3.16～3.23 选择合适的，符合要求的英语文章，逐步完成英文翻译 3.24～5.16 完成论文的主体部分：高抗冲聚苯乙烯的阻燃性能测试及实验数据处理。

5.17～5.31 完成论文的主体部分：阅读文献，补充完善实验结果和分析及计算结果 6.1～6.14 完成论文定稿，修改完善论文做答辩准备