1. 毕业设计（论文）的内容和要求

综合运用所学的化学化工知识，设计合理的实验方案，考察烧成氛围对pd-btese膜的气体渗透性能和分离性能的影响，为该陶瓷膜材料应用于气体分离过程奠定基础。

论文要求学生掌握片式气体分离膜的制备方法及气体膜分离的基本原理。

通过以上实验，培养学生将理论知识应用于处理实际问题的能力、动手能力、实验能力、外文翻译水平和实验数据的处理能力，为今后走向工作岗位提供帮助。

2. 参考文献

[1] B. Ballinger, J. Motuzas, S. Smart, J.C. Diniz da Costa, Palladium cobalt binary doping of molecular sieving silica membranes, Journal of Membrane Science, 451 (2014) 185-191. [2] Chua, Y.; Lin, C. X. C.; Kleitz, F.; Smart, S., Mesoporous organosilica membranes: Effects of pore geometry and calcination conditions on the membrane distillation performance for desalination. Desalination 2015, 370, 53-62. [2] Barelli L, Bidini G, Gallorini F, et al. Hydrogen production through sorption- enhanced steam methane reforming and membrane technology: A review [J]. Energy, 2008, 33(4): 554-570. [3] Metz B, Davidson O, Coninck H, et al. IPCC special report on carbon dioxide capture and storage [M]. UK: Cambrige University Press, 2005, 12: 15-20. [4] Castricum H, Sah A, Kreiter R, et al. Hybrid ceramic nanosieves: stabilizing nanopores with organic links [J]. Chem Commun, 2008, 5: 1103-1105. [5] Wei Q, Wang F, Nie Z, et al. Highly hydrothermally stable microporous silica membranes for hydrogen separation [J]. J Phys Chem B, 2008, 112: 9354-9359. [6] Kanezashi M, Yada K, Yoshioka T, et al. Organic-inorganic hybrid silica membranes with controlled silica network size: Preparation and gas permeation characteristics [J]. J Membr Sci, 2010, 348: 310-318. [7] Lee H R, Shibata T, Tsuru T, et al. Pore-size-controlled silica membranes with disiloxane alkoxides for gas separation [J]. J Membr Sci, 2011, 383: 152-158. [8] Boffa V, Blank D H A, ten Elshof J E, et al. Microporous niobia-silica membranes: In#64258;uence of sol composition and structure on gas transport properties [J]. Microporous Mesoporous Mater, 2009, 118: 202-209. [9] Yun S, Oyama S T. Correlations in palladium membranes for hydrogen separation: A review [J]. Journal of Membrane Science, 2011, 375(1-2): 28-45. [10] Boffa V, Blank D H A, ten Elshof J E, et al. Hydrothermal stability of microporous silica and niobia-silica membranes [J]. J Membr Sci, 2008, 319: 256-263. [11] Masakoto Kanezashi, Mitsunori Sano, Tomohisa Yoshioka, Toshinori Tsuru, Extremely thin Pd-silica mixed-matrix membranes with nano-dispersion for improved hydrogen permeability improved hydrogen permeability [J]. Chemical Communications, 2010, 46(33): 6171-6173. [12] A. L. Ahmad, M. A. T. Jaya, C. J. C. Derek, M. A. Ahmad, Synthesis and characterization of TiO2 membrane with palladium impregnation for hydrogen separation [J]. J. Membr. Sci, 2011, 366(1-2): 166-175. [13]Kanezashi M, Fuchigami D, Yoshioka T, et al. Control of Pd dispersion in sol-gel derived amorphous silica membranes for hydrogen separation at high temperatures [J]. Journal of Membrane Science, 2013, 439: 78-86.

3. 毕业设计（论文）进程安排

01-03周：文献检索阅读、英文资料翻译、设计实验方案、掌握相关实验装置的操作方法，撰写开题报告； 04-07周：合成溶胶，制备非担载膜，表征溶胶、非担载膜的性能； 08-13周：测定膜在0.3 MPa条件下气体渗透性能； 14-16周：整理实验数据，撰写毕业论文。