土壤对重金属镉的吸附性能任务书
2020-04-21 17:14:38
1. 毕业设计(论文)的内容和要求
本课题研究土壤对重金属Cd2 的直接吸附特性,包括静态吸附的动力学和热力学,以及pH和温度及重金属浓度,腐殖酸含量等因素对其吸附解析的影响,结合电镜扫描、红外光谱和XRD等表征分析手段对其机理进行探讨,明确实验土样对镉离子的吸附机理,建立黑腐酸改性理论,揭示其对重金属污染治理的机理。
2. 参考文献
[1]Chi T, Zuo Jiane, Liu F L. Performance and mechanism for cadmium and lead adsorption from water and soil by corn straw biochar. Frontier Environment Science &Engineer, 2017,11(2), 1-8. [2]郑喜坤,鲁安怀,高翔,等.土壤中重金属污染现状与防治方法[J].土壤与环境,2002,11(1):79-84. [3]Nicholson F A, Smith S R, Alloway B J, et al. An inventory of heavy inputs to agricultural soils in England and Wales[J]. The Science of the Total Environment,2003,311(123):205-219. [4]彭绍元,齐志明,黄冠华,等.重金属在夏玉米作物残体中残留特征的田间试验研究[J].灌溉排水学报,2003,22(6):9-13. [5]黄占斌,李昉泽.土壤重金属固化稳定化的环境材料研究进展[J].中国材料进展,2017,36(11):840-851. [6]Zhang J, Dai J, Wang R, et al. Adsorption and desorption of divalent mercury(Hg2 ) on humic acid and fulvic acid extracted from typical soil in china[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2009,335(1-3):194-2-1. [7]Wu Q, You R, Clark M, et al. Pb(Ⅱ)removal from aqueous solution by a low-cost adsorbent dry desulfurization slag[J]. Applied Surface Science,2014,314:129-137. [8]Zhao H, Xia B, Chen F, et al. Human health risk from soil heavy metal contamination under land uses near Dabaoshan Mine,Southern China[J]. Science of the Total Environment, 2012, 417 -418 (7385):45-54. [9]Yip T C, Yan D Y, Yui M M, et al. Heavy metal extraction from an artificially contaminated sandy soil under EDDS deficiency: significance of humic acid and chelant mixture[J]. Chemosphere, 2010,80(4):416-421. [10]Chen W, Habibul N, Liu X Y, et al. FTIR and Synchronous Fluorescence Heterospectral Two-Dimensional Correlation Analyses on the Binding Characteristics of Copper onto Dissolved Organic Matter[J]. Environment Science&Technology,2015,49(4):2052-2058. [11]陈盈,张满利,关连珠,等. pH对不同来源腐殖酸吸附铅和锰的影响[J].中国农学通报, 2010,26(12):67-69. [12]Yang K, Miao G F, Wu W H, et al. Sorption of Cu2 on humic acids sequentially extracted from a sediment[J]. Chemosphere, 2015, 138: 657- 663. [13]Havelcova M, Mizera J, Sykorova I, et al. Sorption of metal ions on lignite and derived humic substances[J]. Journal of Hazardous Material, 2009,161(1):559-564. [14]杜凤龄,王刚,徐敏,等.新型高分子鳌合-絮凝剂制备条件的响应面法优化[J].中国环境科学,2015,35(4):1116-1122. [15]陆中桂,黄占斌,李昂,等.腐植酸对重金属铅镉的吸附特征研究[J],环境科学学报,2018,38(9):3721-3729. [16]Yang K, Miao G F, Wu W H, et al. Sorption of Cu2 on humic acids sequentially extracted from a sediment[J]. Chemosphere, 2015,138:657-663. [17]Qiu Y, Yu S M, Chen L L. Sorption of radiocobalt on acid-activated sepiolite: effects of pH, ionic strength, foreign ions, humic acid and temperature[J]. J Radioanal Nucl Chem 2013, 295:1673#8211;1681. [18]Wu C H, Lin C F, Ma H W, et al. Effect of fulvic acid on the sorption of Cu and Pb onto γ-Al2O3[J]. Water Research .2003,37: 743#8211;752. [19]张丽洁,张瑜,刘德辉.土壤重金属复合污染的化学固定修复研究[J].土壤,2009,(3):420-424. [20]孟凡德,袁国栋,韦婧,等.风化煤提取的胡敏酸对镉的吸附性能及其应用潜力[J].浙江大学学报,2016,42(4):460-468. [21]Zhang J, Wang S, Wang Q, et al. First determination of Cu adsorption on soil humin [J].Environmental Chemistry Letters,2013,11(1):41-46. [22]王雅辉,吕文英,邹雪刚,等.响应面法优化胡敏素对Cu2 的吸附及理研究[J].环境科学学报,2017,37(2) :624-632. [23]Wang Y, Li L, Zou X, et al. Impact of humin on soil adsorption and remediation of Cd(II), Pb(II), and Cu(II) [J].Soil and Sediment Contamination, 2016, 25 (6) :700-715. [24]燕爱春,谢修鸿,范春莹,等.土壤胡敏素对铜离子的吸附作用及其机理研究[J].环境科学学报,2018, http://kns.cnki.net/kcms/detail/11.1843. X. 2018 06 2 5.1542 .005.html [25]Jacundino J S, Santos O S, Santos J C C, et al.Interactions between humin and potentially toxic metals: Prospects for its utilization as an environmental repair agent [J]. Journal of Environmental Chemical Engineering,2015,3(2):708-715. [26]Zhang J, Yin H, Wang H, et al. Reduction mechanism of hexavalent chromium by functional groups of undissolved humic acid and humin fractions of typical black soil from Northeast China [J]. Environemtnal Science and Pollution Research,2018, 25(27):16913-16921. [27]姚爱军,青长乐,牟树森.腐殖酸对汞的络合稳定特性及其环境学意义[J].中国生态农业学报,2006,14(3):138-140. [28]白玲玉,陈世宝,华珞,等.腐植酸与Cd、Zn的络合特性研究[J].核农学报,2000,14(1):44-48.
3. 毕业设计(论文)进程安排
2019.02-2019.03 学习理论知识 汇报、组会 2019.03-2019.04 开题、文献阅读 开题报告 2019.04-2019.05 做实验改进方案 周一汇报、组会 2019.05-2019.06 数据处理,写毕业论文
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