1. 毕业设计（论文）的内容和要求

内容：设计并合成砌块分子，实验筛选砌块分子缩合的条件以获得最佳晶体结构的COF材料，通过XRD辅以materials studio软件模拟计算解析COF的晶体结构并用电化学方法测算其HOMO与LUMO，最后通过荧光滴定实验评估其荧光检测含硝基爆炸物的传感表现并探究COF荧光猝灭机理。

要求：具备较扎实的有机合成基础、查阅文献能力、熟练使用scifinder能力。

2. 参考文献

[1] Ming-Wei Zhu,et al. The construction of fluorescent heteropore covalent organic frameworks and their applications in spectroscopic and visual detection of trinitrophenol with high selectivity and sensitivity[J].Chem. Commun., 2018,54, 2308-2311. [2] Dalapati S, et al. Highly Emissive Covalent Organic Frameworks[J].J. Am. Chem. Soc.,2016, 138, 5797-5800. [3] Wei W, et al. Highly cross-linked fluorescent poly(cyclotriphosphazene-co-curcumin) microspheres for the selective detection of picric acid in solution phase[J].J. Mater. Chem. A,, 2015, 3, 4604-4611. [4] Xue R, et al. Fluorescence properties and analytical applications of covalent organic frameworks[J]. Anal. Methods, 2017, 9, 3737-3750. [5] Yang W, et al. Aggregation-induced emission and intermolecular charge transfer effect in triphenylamine fluorophores containing diphenylhydrazone structures[J]. Phys.Chem.Chem.Phys., 2016, 18, 28052

3. 毕业设计（论文）进程安排

2016-02-24#8212;03-10 查阅国内外有关文献，拟订实验方案。

2016-03-10#8212;03-20 翻译外文文献，并撰写文献综述。

2016-03-20#8212;04-10 按照拟定的实验方案依次进行实验。