1. 毕业设计（论文）的内容和要求

(1) 结合课题的研究，加深对基本理论、基本知识以及课题背景知识的理解。

(2) 能尽快进入课题研究领域展开思考，加强分析问题解决问题的能力。

(3) 学会检索中外文文献，追踪相关课题的最新报道，阅读文献并归纳总结，为以后的学习或工作提供条件。

2. 参考文献

[1] Bhattacharjee S, Chen C, Ahn W S. Chromium terephthalate metal-organic framework MIL-101(Cr): synthesis, functionalization, and applications for adsorption and catalysis [J]. RSC Advances, 2014, 4(94): 52500-52525. [2] F#233;rey G, Mellot-Draznieks C, Serre C, et al. A chromium terephthalate-based solid with unusually large pore volumes and surface area [J]. Science, 2005, 309(5743): 2040-2042. [3] Zhao T, Jeremias F, Boldog I, et al. High-yield, fluoride-free and large-scale synthesis of MIL-101(Cr) [J]. Dalton Transactions, 2015, 44(38): 16791-16801. [4] Bromberg L, Diao Y, Wu H, et al. Chromium(III) terephthalate metal organic framework (MIL-101): HF-free synthesis, structure, polyoxometalate composites, and catalytic properties [J]. Chemistry of Materials, 2012, 24(9): 1664-1675. [5] Hong D Y, Hwang Y K, Serre C, et al. Porous chromium terephthalate MIL-101(Cr) with coordinatively unsaturated sites: surface functionalization, encapsulation, sorption and catalysis [J]. Advanced Functional Materials, 2009, 19(10): 1537-1552. [6] 郭金涛, 陈勇, 荆钰, 等. 以醋酸盐为矿化剂合成金属有机骨架MIL-101(Cr) [J]. 高等学校化学学报, 2012, 33(04): 668-672. [7] Llewellyn P L, Bourrelly S, Serre C, et al. High uptakes of CO2 and CH4 in mesoporous metal organic frameworks MIL-100 and MIL-101 [J]. Langmuir, 2008, 24(14): 7245-7250. [8] Tranchemontagne D J, Mendoza-Cort#233;s J L, O#8217;Keeffe M, et al. Secondary building units, nets and bonding in the chemistry of metal-organic frameworks [J]. Chemical Society Reviews, 2009, 38(5): 1257-1283. [9] Cantu D C, McGrail B P, Glezakou V A. Formation mechanism of the secondary building unit in a chromium terephthalate metal-organic framework [J]. Chemistry of Materials, 2014, 26(22): 6401-6409. [10] Yang J, Zhao Q, Li J, et al. Synthesis of metal-organic framework MIL-101 in TMAOH-Cr(NO3)3-H2BDC-H2O and its hydrogen-storage behavior [J]. Microporous and Mesoporous Materials, 2010, 130(1): 174-179. [11] Khan N A, Jun J W, Jhung S H. Effect of water concentration and acidity on the synthesis of porous chromium benzenedicarboxylates [J]. European Journal of Inorganic Chemistry, 2010, 2010(7): 1043-1048. [12] Livage C, Egger C, F#233;rey G. Hydrothermal versus non-hydrothermal synthesis for the preparation of organic-inorganic solids: the example of Cobalt(II) succinate [J]. Chemistry of Materials, 2001, 13(2): 410-414. [13] Jhung S H, Lee J H, Yoon J W, et al. Microwave synthesis of chromium terephthalate MIL-101(Cr) and its benzene sorption ability [J]. Advanced Materials, 2007, 19(1): 121-124. [14] Khan N A, Kang I J, Seok H Y, et al. Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101(Cr) [J]. Chemical Engineering Journal, 2011, 166(3): 1152-1157.

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 2018.2.25-2018.3.9 查阅收集文献资料，了解课题背景；并整理资料，准备实验药品及实验装置，为正式实验作准备工作； 2018.3.9-2018.5.1 撰写毕业论文开题报告，制备羧酸盐有机配体，并且合成MIL-101(Cr)； 2018.5.1-2018.5.15 纯化MIL-101(Cr)，同时对已经制得的样品进行一系列表征，并且撰写中期自查表； 2018.5.15-2018.6.1 整理并补充实验数据，为撰写论文作准备； 2018.6.1-2018.6.15 撰写论文，准备论文答辩。