1. 毕业设计（论文）的内容和要求

内容：以ctab为表面活性剂，teos为硅源，采用一步水热法制备mcm-41介孔硅。

在合成过程中，原位引入钒源，通过氨水的调控作用，钒源和硅源同时水解，形成”-si-o-v-o-si-”键，制备钒掺杂的介孔mcm-41。

将其应用在苯羟基化实验中，探讨不同的反应条件对催化活性的影响。

2. 参考文献

[1] Kong Y, Zhang R, XU X J, et al. Synthesis and Characterization of V-MCM41 with High Vanadium Content [J]. Chinese J Inorg Chem, 2008, (24):1124-1127. [2] Wang Y, Zhang Q H, Ohishi Y, et al. Synthesis of V-MCM-41 by Template-Ion Exchange Method and Its Catalytic Properties in Propane Oxidative Dehydrogenation[J]. Catal Lett. 2001, 72 (3-4):215~219. [3] Huo Q, Margolese D I, Ciesla U, et al. Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays[J]. Chem Mater, 1994, 6 [4] Chen S Y, Tang C Y, Chuang W T, et al. A facile route to synthesizing functionalized mesoporous SBA-15 materials with platelet morphology and short mesochannels[J]. Chem Mater, 2008, 20 (12): 3906-3916. [5] Huo Q, Margolese D I, Ciesla U. Generalized synthesis of periodic surfactant/inorganic composite materials[J]. Nature, 1994, 368:317-321. [6] Liu X, Tian B, Yu C, et al. Room-Temperature Synthesis in Acidic Media of Large-Pore Three-Dimensional Bicontinuous Mesoporous Silica with Ia3d Symmetry[J]. Angew. Chem .Int. Edit. 2010, 41 (20): 3876~3878. [7] Nie D X, Liang Y, Zhou, T S, et al. FDU-15-Pt Composites with Different Pt Loading and Their Electrocatalytic Reduction to Ultratrace Nitroaromatic Compounds[J]. Int J Environ An Ch. 2012, 7(92): 832~843. [8] Tozuka Y, Wongmekiat A , Kimura K, et al. Effect of Pore Size of FSM-16 on The Entrapment of Flurbiprofen in Mesoporous Structures[J]. Chem Pharm Bull.2005,53(8): 974~977. [9] Jin D F, Hu G B, Jin H X, et al. Synthesis of Sulfated Zirconia by Grafting on Mesoporous SBA-15 by Sol-Gel Method[J]. Rare Metal Mat Eng , 2012, 41(53): 379~382.

3. 毕业设计（论文）进程安排

2018-03-1#8212;03-9 查阅国内外有关文献，拟订实验方案。

2018-03-9#8212;03-21 翻译外文文献，并撰写文献综述。

2018-03-21#8212;04-8 按照拟定的实验方案依次进行实验。