1. 毕业设计（论文）的内容和要求

1. 查阅、整理文献资料，加深对自己课题的理解，并撰写开题报告； 2. 要求学生对工业催化、无机材料制备基础、波谱分析等学科复习，从而对以后催化剂活性测试实验、谱图分析打下基础。

3. 主要研究钴锰复合氧化物的制备，将其负载到钛白粉上，制得负载型钴锰复合氧化物催化剂，并用xrd、bet、sem电镜等表征手段进行表征。

4. 利用已制备出的负载型钴锰复合氧化物催化剂进行甲苯催化燃烧反应，考察不同活性组分配伍及不同负载量对催化燃烧性能的影响。

2. 参考文献

[1] 潘红艳, 张煜, 林倩,等. 催化燃烧VOCs用非贵金属催化剂研究新进展[J]. 化工进展, 2011, 30(8):1726-1732. [2] 程高, 余倩, 杨俊涛,等. 铜锰复合氧化物粉体的制备及其对甲苯催化燃烧性能[J]. 中国粉体技术, 2014, 20(4):20-23. [3] 何曦, 刘胜强, 何淼,等. 催化燃烧工艺处理有机废气污染物分析[J]. 中国环保产业, 2016(11):34-38. [4] Barakat T, Idakiev V, Cousin R, et al. Total oxidation of toluene over noble metal based Ce, Fe and Ni doped titanium oxides[J]. Applied Catalysis B Environmental, 2014, 146(5):138-146. [5] Liu P, He H, Wei G, et al. An efficient catalyst of manganese supported on diatomite for toluene oxidation: Manganese species, catalytic performance, and structure-activity relationship[J]. Microporous Mesoporous Materials, 2017, 239:101-110. [6] Shi Z, Yang P, Tao F, et al. New insight into the structure of CeO2 #8211;TiO2, mixed oxides and their excellent catalytic performances for 1,2-dichloroethane oxidation[J]. Chemical Engineering Journal, 2016, 295:99-108. [7] 李锦卫, 朱佳. 负载型CuMnOx/TiO2催化剂催化燃烧甲苯[J]. 工业催化, 2015, 23(12):1002-1007. [8] Vu V H, Belkouch J, Ould-Dris A, et al. Catalytic oxidation of volatile organic compounds on manganese and copper oxides supported on titania[J]. Aiche Journal, 2008, 54(6):1585#8211;1591. [9] Abouka#239;s A, Abi-Aad E, Taouk B. Supported manganese oxide on TiO2, for total oxidation of toluene and polycyclic aromatic hydrocarbons (PAHs): Characterization and catalytic activity[J]. Materials Chemistry Physics, 2013, 142(2#8211;3):564-571. [10] Jung S C, Park Y K, Jung H Y, et al. Effects of calcination and support on supported manganese catalysts for the catalytic oxidation of toluene as a model of VOCs[J]. Research on Chemical Intermediates, 2016, 42(1):1-15. [11] Vu V H, Belkouch J, Ould-Dris A, et al. Removal of hazardous chlorinated VOCs over Mn#8211;Cu mixed oxide based catalyst[J]. Journal of Hazardous Materials, 2009, 169(1#8211;3):758-765. [12] Suh M J, Park Y K, Ihm S K. One-pot synthesis of perovskite-type metal oxides via confined mesopore and their catalytic activity for toluene oxidation[J]. Catalysis Today, 2016, 265:210-217. [13] Hou Z, Feng J, Lin T, et al. The performance of manganese-based catalysts with Ce0.65Zr0.35O2 as support for catalytic oxidation of toluene[J]. Applied Surface Science, 2017. [14] Kim J, Min Y H, Lee N, et al. In Situ Spectroscopic and Computational Studies on a MnO2#8211;CuO Catalyst for Use in Volatile Organic Compound Decomposition[J]. 2017, 2(10):7424-7432. [15] Gan L, Chen J, Peng Y, et al. NOx Removal over V2O5/WO3#8211;TiO2 Prepared by a Grinding Method: Influence of the Precursor on Vanadium Dispersion[J]. Industrial Engineering Chemistry Research, 2017. [16] Tian Z Y, Ngamou P H T, Vannier V, et al. Catalytic oxidation of VOCs over mixed Co#8211;Mn oxides[J]. Applied Catalysis B Environmental, 2012, s 117#8211;118(3):125-134.

3. 毕业设计（论文）进程安排

2018.2.26-2018.3.20 查阅课题相关文献资料，确定实验思路，撰写开题报告 2018.3.21-2018.5.25 负载型钴锰复合氧化物催化剂的制备，对制备出的催化剂进行性能评价从而确定最终实验方案，考察一系列的制备条件对催化剂的性能影响，然后有选择性的对所制备的催化剂进行XRD、BET、FT-IR、SEM等一系列的表征 2018.5.26-2018.6.7 论文撰写