1. 毕业设计（论文）的内容和要求

1、理解甲苯歧化与烷基转移反应过程，阅读相关文献掌握课题研究现状并整理； 2、掌握pt负载的MOR催化剂制备实验技能，了解相关表征手段，详尽客观记录实验数据并做相关分析； 3、按规范格式书写毕业论文并积极准备PPT答辩。

2. 参考文献

[1] 崔明, 我国对二甲苯的市场分析[J]. 精细与专用化学品. 2018, 6(12): 9-12. [2] 王兆瑞, 叶帅与张森, 原料组成对甲苯歧化和烷基转移反应的影响[J]. 聚酯工业, 2016. 29(06): 11-16. [3] 韩文华, 芳烃PX生产技术展望[J]. 天津化工. 2018, 32(05): 3-5. [4] 宗弘元,陈亮, 对二甲苯装置节能与扩能技术探讨[J]. 石油化工. 2015, 44(05): 529-535. [5] Das J, Bhat Y S, Halgeri A B. Transalkylation and disproportionation of toluene and C9 aromatics over zeolite beta[J]. Catalysis Letters, 1994, 23(1-2):161-168. [6] Xiong Y, Rodewald P G, Chang C D. On the Mechanism of Toluene Disproportionation in a Zeolite Environment[J]. Journal of the American Chemical Society, 1995, 117(37):9427-9431. [7] Svelle S, Olsbye U, Lillerud K P, et al. Diphenylmethane-mediated transmethylation of methylbenzenes over H-zeolites[J]. Journal of the American Chemical Society, 2006, 128(17):5618. [8] Dumitriu E, Hulea V, Kaliaguine S, et al. Transalkylation of the alkylaromatic hydrocarbons in the presence of ultrastable Y zeolites Transalkylation of toluene with trimethylbenzenes[J]. Applied Catalysis A General, 1996, 135(1):57-81. [9] Li Y, Wang H, Dong M, et al. Effect of zeolite pore structure on the diffusion and catalytic behaviors in the transalkylation of toluene with 1,2,4-trimethylbenzene[J].Rsc Advances,2015, 5(81):66301-66310. [10] Cha, S.H. and S.B. Hong, Reaction intermediates and mechanism of the zeolite-catalyzed transalkylation of 1,2,4-trimethylbenzene with toluene[J]. Journal of Catalysis, 2018. 357: 1-11. [11] Wang, I., T.C. Tsai and S.T. Huang, Disproportionation of toluene and of trimethylbenzene and their transalkylation over zeolite beta. Industrial Engineering Chemistry Research, 1990, 29:2005-2012. [12] Li, Yanchun, Wang, et al. Optimization of Reaction Conditions in the Transalkylation of Toluene with 1,2,4-Trimethylbenzene Catalyzed by Beta Zeolite and the Investigation of Its Reaction Mechanism[J]. Acta Chimica Sinica, 2016, 13(1):24-52. [13] Meshram N R, Kulkarni S B, Ratnasamy P. Transalkylation of toluene with C9 aromatic hydrocarbons over ZSM5 zeolites[J]. Journal of Chemical Technology Biotechnology, 2010, 34(3):119-126. [14] Barakat Y, Mikhail S, Ayoub S M. Effect of feed composition on product distribution in the catalytic conversion of trimethylbenzenes over ja:math zeolite catalyst[J]. Zeolites, 1987, 7(3):235-239. [15] Das J, BHAT, Y. S, et al. Zeolite beta catalyzed C7 and C9 aromatics transformation[J]. Applied Catalysis A General, 1994, 116(6):71-79. [16] Krej#269;#237; A, Al-Khattaf S, Ali M A, et al. Transalkylation of toluene with trimethylbenzenes over large-pore zeolites[J]. Applied Catalysis A General, 2010, 377(1):99-106. [17] Almulla F M, Zholobenko V I, Patrick I. Hill, et al. Transalkylation of Toluene with 1,2,4-Trimethylbenzene over Large Pore Zeolites[J]. Industrial Engineering Chemistry Research, 2017, 56(35):acs.iecr.7b01388. [18] Wu J C, Leu L J. Toluene disproportionation and transalkylation reaction over mordenite zeolite catalysts[J]. Applied Catalysis, 1983, 7(3):283-294. [19] Liu, N, et al. A facile strategy for preparation of phosphorus modified HZSM-5 shape-selective catalysts and its performances in disproportionation of toluene[J]. Catalysis Communications, 2016. 77: 60-64. [20] Waal J C V D, Bekkum H V. Molecular Sieves, Multifunctional Microporous Materials in Organic Synthesis[J]. Journal of Porous Materials, 1998, 5(3-4):289-303.

3. 毕业设计（论文）进程安排

2-3月：文献检索及撰写开题报告； 3-4月：Pt负载的MOR催化剂的制备与表征； 4-5月：固定床反应条件考察； 5-6月：毕业论文撰写与修正。