1. 毕业设计（论文）的内容和要求

内容： 金属矿冶炼、电解、电镀等行业每年要排放大量含重金属离子的废水，重金属废水排放到环境中不能被微生物降解，并通过土壤、水、空气，尤其是食物链，对人类健康、动植物及水生生物产生严重危害。

近年来随着表面处理技术的发展，电镀、化学镀被广泛应用，而这种工艺中大量使用的络合剂，使重金属废水的成分更加复杂。

以电镀行业重金属废水为例：电镀废水中含有铜、镍、镉、铅、铬等有毒有害重金属离子、氰化物、乙二胺四乙酸（edta）以及表面活性剂、光亮剂、防染盐等污染物。

2. 参考文献

[1] Sillanp M E T, Kurniawan T A, Lo W H. Degradation of chelating agents in aqueous solution using advanced oxidation process (AOP) [J]. Chemosphere. 2011, 83(11):1443-1460. [2] Zou Y, Wang X, Khan A, Wang P, Liu Y, Alsaedi A, Hayat T, Wang X. Environmental remediation and application of nanoscale zero-valent iron and its composites for the removal of heavy metal ions: a review [J]. Environmental Science Technology. 2016, 50(14): 7290-7304. [3] Vega F A, Weng L. Speciation of heavy metals in River Rhine [J]. Water research. 2013, 47(1): 363-372. [4] Zhao X, Guo L, Hu C, Liu H, Qu J. Simultaneous destruction of Nickel (II)-EDTA with TiO2/Ti film anode and electrodeposition of nickel ions on the cathode [J]. Applied Catalysis B: Environmental. 2014, 144: 478-485. [5] Wu P, Zhou J, Wang X, Dai Y, Dang Z, Zhu N, Li P, Wu J. Adsorption of Cu-EDTA complexes from aqueous solutions by polymeric Fe/Zr pillared montmorillonite: Behaviors and mechanisms [J]. Desalination. 2011, 277(1): 288-295. [6] Wu L, Wang H, Lan H, Liu H, Qu J. Adsorption of Cu(II)#8211;EDTA chelates on tri-ammonium-functionalized mesoporous silica from aqueous solution [J]. Separation and Purification Technology. 2013, 117: 118-123. [7] Xu Z, Shan C, Xie B, Liu Y, Pan B. Decomplexation of Cu(II)-EDTA by UV/persulfate and UV/H2O2: Efficiency and mechanism [J]. Applied Catalysis B: Environmental. 2017, 200: 439-447. [8] Zhen H B，Xu Q，Hu Y Y，et al. Characteristics of heavy metals capturing agent dithiocarbamate (DTC) for treatment of ethylene diamine tetraacetic acid-Cu(EDTA-Cu) contaminated wastewater [J]. Chemical Engineering Journal. 2012, 209: 547-557. [9] Jiang S X, Qu J X, Xiong Y. Removal of chelated copper from wastewaters by Fe2 -based replacement-precipitation [J]. Environmental Chemistry Letters. 2010, 8(4): 339-342. [10] Xu Z, Gao G, Pan B, Zhang W, Lv L. A new combined process for efficient removal of Cu(II) organic complexes from wastewater: Fe(III) displacement/UV degradation/alkaline precipitation [J]. Water research. 2015, 87: 378-384. [11] Lan S H, Ju F, Wu X W. Treatment of wastewater containing EDTA-Cu(Ⅱ) using the combined process of interior microelectrolysis and Fenton oxidation-coagulation [J]. Separation and Purification Technology. 2012, 89: 117-124. [12] Chen F Y, Zhao X, Liu H J, et al. Reaction of Cu(CN)32-with H2O2 in water under alkaline conditions: Cyanide oxidation, Cu /Cu2 catalysis and H2O2 decomposition [J]. Applied Catalysis B: Environmental. 2014, 158/159: 85-90. [13] Guan X, Jiang X, Qiao J, Zhou G. Decomplexation and subsequent reductive removal of EDTA-chelated Cu(II) by zero-valent iron coupled with a weak magnetic field: Performances and mechanisms [J]. Journal of Hazardous Materials. 2015, 300: 688-694. [14] Pachuau L, Lee S M, Tiwari D. Ferrate(Ⅵ) in wastewater treatment contaminated with metal (Ⅱ)-iminodiacetic acid complexed species [J]. Chemical Engineering Journal. 2013, 230: 141-148. [15] Zhao X, Wang Haidong, Chen Fayuan, et al. Efficient treatment of an electroplating wastewater containing heavy metal ions, cyanide, and organics by H2O2 oxidation followed by the anodic Fenton process [J]. Water Science and Technology. 2013, 68(6): 1329-1335.

3. 毕业设计（论文）进程安排

2019.1～2019.3 查阅文献，撰写文献综述和开题报告，并修改开题报告。

2019.3～2019.5 实验阶段（制定实验步骤、实验方案、实验、分析实验数据、补充实验） 2019.5～2019.6.10 撰写论文、修改论文，准备答辩。