1. 毕业设计（论文）的内容和要求

碳酸丙烯酯为一种无色无臭的易燃液体。

与乙醚、丙酮、苯、氯仿、醋酸乙烯等互溶，溶于水和四氯化碳。

对二氧化碳的吸收能力很强，性质稳定。

2. 参考文献

[1]利用磷尾矿催化合成碳酸丙烯酯.雷汉民;文武强;肖艳华;杜治平.矿产保护与利用 [2]低共熔剂在碳酸丙烯酯合成中的应用[D]. 吴凯.烟台大学.2018 [3]氧化镁/氧化铝催化二氧化碳合成碳酸丙烯酯的应用研究[D]. 赵黎业.新疆大学.2018 [4]尿素法合成碳酸丙烯酯反应研究[D]. 张斌.郑州大学.2017 [5]环状碳酸酯的合成工艺研究[D]. 刘瑛.浙江大学.2016 [6]四叔丁基金属酞菁催化活化CO2与环氧丙烷的环加成反应[J]. 张英菊;梁斌;潘玉珍;何仁.催化学报.2003(10) [7]MOFs-聚离子液体杂化材料的制备及其催化CO2合成环状碳酸酯的研究 杨万园.南昌航空大学 .2018 [8]碳酸丙烯酯生产工艺分离工段的模拟优化.李瑞端; 王佳楠; 张薇; 戴传波.现代化工 [9]CO2与环氧丙烷合成碳酸丙烯酯的多相催化剂研究.张建; 张志智; 孙潇磊; 孙万付; 方向晨.天然气化工(C1化学与化工).2015 [10]硅胶负载[H2N-PECH-MIM]Cl及催化合成碳酸丙烯酯 郭立颖; 邓莉莉; 马秀云; 金先超; 殷龙珠.化学研究与应用.2017 [11]Reusable and efficient polymer nanoparticles grafted with hydroxyl-functionalized phosphonium-based ionic liquid catalyst for cycloaddition of CO2 with epoxides[J] . Weili Dai,Ya Zhang,Ying Tan,Xubiao Luo,Xinman Tu. Applied Catalysis A, General . 2016 [12]Cycloaddition of CO2 and epoxides catalyzed by dicationic ionic liquids mediated metal halide: Influence of the dication on catalytic activity[J] . Mengshuai Liu,Lin Liang,Tao Liang,Xiaoli Lin,Lei Shi,Fangxiao Wang,Jianmin Sun. Journal of Molecular Catalysis. A, Chemical . 2015 [13]Efficiency of DBU/iodine cooperative dual catalysis for the solvent-free synthesis of five-membered cyclic carbonates under atmospheric CO2 pressure[J] . Olivier Coulembier,S#233;bastien Moins,Vincent Lemaur,Roberto Lazzaroni,Philippe Dubois. Journal of CO2 Utilization . 2015 [14]Mechanism of fixation of CO2 in the presence of hydroxyl-functionalized quaternary ammonium salts[J] . Li Wang,Ping Li,Xiangfeng Jin,Jinglai Zhang,Hongyan He,Suojiang Zhang. Journal of CO2 Utilization . 2015 [15]Synthesis, Culture Medium Stability, and In Vitro and In Vivo Zebrafish Embryo Toxicity of Metal#8211;Organic Framework Nanoparticles[J] . #224;ngels Ruyra,Amirali Yazdi,Jordi Esp#237;n,Arnau Carn#233;‐S#225;nchez,Nerea Roher,Julia Lorenzo,Inhar Imaz,Daniel Maspoch. Chem. Eur. J. . 2015 (6) [16]Hydroxy‐Functionalized Imidazolium Bromides as Catalysts for the Cycloaddition of CO2 and Epoxides to Cyclic Carbonates[J] . Michael H. Anthofer,Michael E. Wilhelm,Mirza Cokoja,Markus Drees,Wolfgang A. Herrmann,Fritz E. K#252;hn. ChemCatChem . 2015 (1) [17]Amino-Functional Imidazolium Ionic Liquids for CO2 Activation and Conversion to Form Cyclic Carbonate[J] . Chengtao Yue,Dan Su,Xu Zhang,Wei Wu,Linfei Xiao. Catalysis Letters . 2014 (7) [18]Functionalized zeolitic imidazolate framework F-ZIF-90 as efficient catalyst for the cycloaddition of carbon dioxide to allyl glycidyl ether[J] . Tharun Jose,Yeseul Hwang,Dong-Woo Kim,Moon-Il Kim,Dae-Won Park. Catalysis Today . 2014 [19]Bioconjugation of MOF-5 for molecular sensing[J] . Pawan Kumar,Akash Deep,A. K. Paul,L. M. Bharadwaj. Journal of Porous Materials . 2014 (1) [20]Mechanism and origins of enantioselectivity for [BMIM]Cl ionic liquids and ZnCl2 co-catalyzed coupling reaction of CO2 with epoxides[J] . Fang Wang,Chuanzhi Xu,Zhen Li,Chungu Xia,Jing Chen. Journal of Molecular Catalysis. A, Chemical . 2014 [21]Metal#8211;organic frameworks of zeolitic imidazolate framework-7 and zeolitic imidazolate framework-60 for fast mercury and methylmercury speciation analysis[J] . Fujian Xu,Lu Kou,Jia Jia,Xiandeng Hou,Zhou Long,Shanling Wang. Analytica Chimica Acta . 2013 [22]Cyclic carbonates synthesis from epoxides and CO2 over metal#8211;organic framework Cr-MIL-101[J] . Olga V. Zalomaeva,Andrey M. Chibiryaev,Konstantin A. Kovalenko,Oxana A. Kholdeeva,Bair S. Balzhinimaev,Vladimir P. Fedin. Journal of Catalysis . 2013 [23]Functionalized IRMOF-3 as efficient heterogeneous catalyst for the synthesis of cyclic carbonates[J] . Xi Zhou,Yi Zhang,Xiangui Yang,Liangzhong Zhao,Gongying Wang. Journal of Molecular Catalysis. A, Chemical . 2012 [24]Tetramethylguanidine#8211;silica nanoparticles as an efficient and reusable catalyst for the synthesis of cyclic propylene carbonate from carbon dioxide and propylene oxide[J] . Farook Adam,Muazu Samaila Batagarawa. Applied Catalysis A, General . 2012 [25]Water as an efficient medium for the synthesis of cyclic carbonate[J] . Jian Sun,Junyi Ren,Suojiang Zhang,Weiguo Cheng. Tetrahedron Letters . 2008 (4) [26]Hydroxyl-functionalized ionic liquid: a novel efficient catalyst for chemical fixation of CO2 to cyclic carbonate[J] . Jian Sun,Suojiang Zhang,Weiguo Cheng,Junyi Ren. Tetrahedron Letters . 2008 (22) [27]Guanidinium Salt Functionalized PEG: An Effective and Recyclable Homo-geneous Catalyst for the Synthesis of Cyclic Carbonates from CO2 and Epoxides under Solvent-Free Conditions[J] . Xiao-Yong Dou,Jin-Quan Wang,Ya Du,Er Wang,Liang-Nian He. Synlett . 2007 (19) [28]Solventless synthesis of cyclic carbonates from carbon dioxide and epoxides catalyzed by silica-supported ionic liquids under supercritical conditions[J] . Jin-Quan Wang,Xiao-Dong Yue,Fei Cai,Liang-Nian He. Catalysis Communications . 2006 (2) [29]ZnCl 2 /phosphonium halide: An efficient Lewis acid/base catalyst for the synthesis of cyclic carbonate[J] . Jian Sun,Lei Wang,Suojiang Zhang,Zengxi Li,Xiangping Zhang,Wenbin Dai,Ryohei Mori. Journal of Molecular Catalysis. A, Chemical . 2006 (1) [30]Highly active, hexabutylguanidinium salt/zinc bromide binary catalyst for the coupling reaction of carbon dioxide and epoxides[J] . Haibo Xie,Shenghai Li,Suobo Zhang. Journal of Molecular Catalysis. A, Chemical . 2006 (1)

3. 毕业设计（论文）进程安排

2018.12.26~2019.1.10 查找相关资料 2019.1.11~2019.1.13 整理收集的文献资料，编写开题报告和外文翻译，同时构思论文的框架 2019.1.14~2019.1.16 完成开题报告和外文翻译，并进一步完成论文的文献综述部分 2019.1.17~2019.3.20 深入了解合成碳酸丙烯酯的工艺方法 2019.3.21~2019.4.20 根据工艺过程，进行安全分析，对可能存在的危险有害因素进行详细剖析 2019.4.21~2019.5.15 根据危险有害因素，提出安全防护措施和控制措施 2019.5.16~2019.6.05 完成论文粗稿 2019.6.06~2019.6.20 修改并完善论文，准备答辩