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毕业论文网 > 任务书 > 化学化工与生命科学类 > 化学工程与工艺 > 正文

季鏻盐离子液体催化合成PMA的研究任务书

 2020-04-26 12:49:40  

1. 毕业设计(论文)的内容和要求

查阅相关文献资料,能够读懂英文文献;综合文献中的实验方法,设计与课题相关的条件实验;开展各个不同的条件实验,在实际操作过程中要能够分析并解决突发问题,能够对不同的实验结果进行分析对比;通过核磁光谱对目标产物进行鉴定,能够对谱图进行分析;最后完成撰写本课题论文的任务。

2. 参考文献

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[6] 王治明. 离子液体的合成及其在有机合成中的应用[D]:[博士学位论文]. 杭州: 浙江大学理学院, 2007. [7] Wilkes J S, Levisky J A, Pflug J L, et al. Composition determinations of liquid chloroaluminate molten salts by nuclear magnetic resonance spectrometry[J]. Analytical Chemistry, 1982,54(13):2378-2379. [8] Wilkes J S. Air and Water Stable I-Ethyl-3-methylimidazolium Based Ionic Liquids[J]. Cheminform, 1992,13(25):166. [9] Tseng C, Chang J, Chen J, et al. Corrosion behaviors of materials in aluminum chloride#8211;1-ethyl-3-methylimidazolium chloride ionic liquid[J]. Electrochemistry Communications, 2010,12(8):1091-1094. [10] Earle M J, Seddon K R. Ionic liquids. Green solvents for the future[J]. Pure Applied Chemistry, 2000,72(7):1391-1398. [11] Qing He, Jeremy W. O'Brien, Kayla A. Kitselman, et al. Synthesis of cyclic carbonates from CO2 and epoxides using ionic liquids and related catalysts including choline chloride #8211; metal halide mixtures[J]. Catalysis Science Technology, 2014,46(4):1513. [12] Vekariya R L. A review of ionic liquids: Applications towards catalytic organic transformations[J]. Journal of Molecular Liquids, 2017,227:44-60. [13] Guajardo N V, Carlesi C, Schrebler R, et al. Applications of Liquid/ Liquid Biphasic Oxidations by Hydrogen Peroxide Using Ionic Liquids or Deep Eutectic Solvents[J]. Chempluschem, 2017,82(2):165. [14] Poole C F, Lenca N. Applications of the solvation parameter model in reversed-phase liquid chromatography[J]. Journal of Chromatography A,2016 [15] Martino W, de la Mora J F, Yoshida Y, et al. Surface tension measurements of highly conducting ionic liquids[J]. Green Chemistry, 2006,8(4):390. [16] Cole A C, Jensen J L, Ntai I, et al. Novel Broslash;nsted Acidic Ionic Liquids and Their Use as Dual Solvent#8722;Catalysts[M]. 2002: 5962-5963. [17] Liu J, Yin D, Yin D, et al. ZnCl 2 supported on NaY zeolite by solid-state interaction under microwave irradiation and used as heterogeneous catalysts for high regioselective Diels#8211;Alder reaction of myrcene and acrolein[J]. Journal of Molecular Catalysis a Chemical, 2004,209(1):171-177. [18] Earle M J, Mccormac P B, Seddon K R. Regioselective alkylation in ionic liquids[J]. Chemical Communications, 1998,20(20):2245-2246. [19] Hong K, Zhang H, Mays J W, et al. Conventional free radical polymerization in room temperature ionic liquids: a green approach to commodity polymers with practical advantages[J]. Chemical Communications, 2002(13):1368-1369. [20] Shi F. Highly efficient ionic liquid-mediated palladium complex catalyst system for the oxidative carbonylation of amines[J]. Journal of Catalysis, 2003,219(2):372-375. [21] 丁飞, 楼兰兰, 于凯, 等. 离子液体在苯乙酮不对称加氢反应中的应用[J]. 化学工业与工程, 2013,30(06):11-14. [22] 王恩锋, 谭文群, 龙在安. 丙二醇甲醚醋酸酯的合成研究[J]. 精细化工中间体, 2003,33(4):16-17. [23] 金照生, 张卫东, 张磊, 等. 丙二醇甲醚乙酸酯的合成研究[J]. 精细化工, 2001(07):376-378. [24] 马艺文, 孙帅婷, 许冬玲, 等. 酯化反应中催化剂的研究进展[J]. 精细与专用化学品, 2008,16(7):27-30. [25] 邢其毅. 基础有机化学[M]. 高等教育出版社, 2009. [26] Alismaeel Z T, Abbas A S, Albayati T M, et al. Biodiesel from batch and continuous oleic acid esterification using zeolite catalysts[J]. Fuel, 2018,234:170-176. [27] Dal Pozzo D M, Azevedo Dos Santos J A, J#250;nior E S, et al. Free fatty acids esterification catalyzed by acid Faujasite type zeolite[J]. Rsc Advances, 2019 (9): 49-497. [28] 贾荣荣, 张艳章, 李兴波, 等. 丙二酸二异丙酯的合成工艺研究[J]. 山东化工, 2016,45(07):51-55. [29] Huang Z, Lin Y, Li L, et al. Preparation and shaping of solid acid SO42#8722;/TiO2 and its application for esterification of propylene glycol monomethyl ether and acetic acid[J]. Chinese Journal of Chemical Engineering, 2017,25(9):1207-1216. [30] 栾庆洁, 李思佳, 刘丽君, 等. 新型硅钨酸有机盐的合成及催化油酸酯化[J]. 化学试剂, 2018,40(03):207-211. [31] 李媚, 袁宇, 覃琴, 等. 离子交换树脂催化柠檬酸与正丁醇酯化反应动力学研究[J]. 化学世界, 2017,58(06):353-358. [32] 傅俊红, 沈荣飞. 改性离子树脂催化油酸二氯丙醇酯的合成[J]. 广东化工, 2016,43(09):86-87. [33] Fang D, Zhou X, Ye Z, et al. Broslash;nsted Acidic Ionic Liquids and Their Use as Dual Solvent#8722;Catalysts for Fischer Esterifications[J]. Industrial Engineering Chemistry Research, 2006,45(24):7982-7984. [34] 尹银, 高健, 廉红蕾, 等. SO_3H-功能化酸性离子液体催化合成己二酸二丁酯[J]. 精细化工, 2015,32(06):652-657. [35] 胡晶晶, 赵地顺, 李静静, 等. 己内酰胺功能化离子液体的合成及其催化酯化性能的研究[J]. 有机化学, 2015:1773-1780.

3. 毕业设计(论文)进程安排

2019.02.25-2019.03.15 查阅国内外有关文献,做文献综述;拟定实验方案。

2019.03.18-2019.05.17 按照实验要求进行各种实验工作。

2019.05.20-2019.05.31进行实验数据的处理,补充有关实验,开始撰写论文。

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