1. 毕业设计（论文）的内容和要求

1、查阅有zif-8，球磨法制备zif-8的相关文献，弄清楚课题的研究目的和意义，掌握课题的研究重点，筛选出与本课题相关性高的文献。

同时阅读课题的相关外文文献，进行总结归纳，并设计实验方案，制定实验计划。

2、熟悉实验仪器的正确使用，提高实验操作技能，合理规划实验进程。

2. 参考文献

[1] Rui Li,a Xiaoqian Ren,a Hongwei Ma,a Xiao Feng,a Zhengguo Lin,a Xingguo Li,b Changwen Hu*a and Bo Wang*a. Nickel-substituted zeolitic imidazolate frameworks for time-resolved alcohol sensing and photocatalysis under visible light. J. Mater. Chem. A, 2014, 2, 5724 [2] Aleksandra Schejn,a Lavinia Balan,b V#233;ronique Falk,a Lionel Aranda,c Ghouti Medjahdic and Raphaeuml;l Schneider*a. Controlling ZIF-8 nano- and microcrystal formation and reactivity through zinc salt variations CrystEngComm, 2014, 16, 4493 [3] Matthew J. Cliffe,b Cristina Mottillo,a Robin S. Stein,c Dejan-Kresimir Bucarb and Tomislav Frisci_c*ab . [4] Shunsuke Tanaka,*ab Koji Kida,a Takuya Nagaoka,a Takehiro Otaa and Yoshikazu Miyakeab . Mechanochemical dry conversion of zinc oxide to zeolitic imidazolate framework. Chem. Commun., 2013, 49, 7884 [5] Cristina Mottillo,a Yuneng Lu,a Minh-Hao Pham,b Matthew J. Cliffe,c Trong-On Dob and Tomislav Fri#353;c#780;ic#769;*a . Mineral neogenesis as an inspiration for mild, solvent-free synthesis of bulk microporous metal#8211;organic frameworks from metal (Zn, Co) oxides. Green Chem., 2013, 15, 2121 [6] Rui Li,a Xiaoqian Ren,a Jingshu Zhao,a Xiao Feng,a Xin Jiang,b Xinxin Fan,c Zhengguo Lin,a Xingguo Li,c Changwen Hu*a and Bo Wang*a. Polyoxometallates trapped in a zeolitic imidazolate framework leading to high uptake and selectivity of bioactive molecules. J. Mater. Chem. A, 2014, 2, 2168 [7] Rui Li,a Xiaoqian Ren,a Hongwei Ma,a Xiao Feng,a Zhengguo Lin,a Xingguo Li,b Changwen Hu*a and Bo Wang*a. Nickel-substituted zeolitic imidazolate frameworks for time-resolved alcohol sensing and photocatalysis under visible light. J. Mater. Chem. A, 2014, 2, 5724 [8] Deborah Crawford,a Jose #769; Casaban,b Robert Haydon,a Nicola Giri,a Tony McNallyc and Stuart L. James*ab .Synthesis by extrusion: continuous, large-scale preparation of MOFs using little or no solvent. Chem. Sci., 2015, 6, 1645 [9] Yu-Ri Lee, Min-Seok Jang, Hye-Young Cho, Hee-Jin Kwon, Sangho Kim, Wha-Seung Ahn. ZIF-8: A comparison of synthesis methods. Chemical Engineering Journal 271 (2015) 276#8211;280 [10] Athanassios D. Katsenis, Andreas Puˇskaric #769;, Vjekoslav Sˇtrukil1,, Cristina Mottillo, Patrick A. Julien, Krunoslav Uzˇarevic #769;, Minh-Hao Pham, Trong-On Do, Simon A.J. Kimber, Predrag Lazic #769;, Oxana Magdysyuk, Robert E. Dinnebier, Ivan Halasz Tomislav Frisˇcˇic #769;. In situ X-ray diffraction monitoring of a mechanochemical reaction reveals a unique topology metal-organic framework. 10.1038/ncomms7662 [11] (a) M. Meilikhov, S. Furukawa, K. Hirai, R. A. Fischer and S. Kitagawa, Angew. Chem., Int. Ed., 2013, 52, 341; (b) J. Du and R. K. O'Reilly, Chem. Soc. Rev., 2011, 40, 2402. [12] (a) G. Lu, O. K. Farha, L. E. Kreno, P. M. Schoenecker, K. S. Walton, R. P. Van Duyne and J. T. Hupp, Adv. Mater., 2011, 23, 4449; (b) B. Chen, Y. Yang, F. Zapata, G. Lin, G. Qian and E. B. Lobkovsky, Adv. Mater., 2007, 19, 1693; (c) B. P. Biswal, D. B. Shinde, V. K. Pillai and R. Banerjee, Nanoscale, 2013, 5, 10556. [13] ZHANG Y M, LI B Y, KRISHNA R, et al. Highly selective adsorption of ethylene over ethane in a MOF featuring the combination of open metal site and π-complexation[J]. Chemical Communications, 2015, 51: 2714-2727. [14] LIN R B, XIANG S C, XING H B, et al. Exploration of porous metal-organic frameworks for gas separation and purification[J]. Coordination Chemistry Reviews, 2017, DOI: 10.1016/j.ccr.2017. 09.027. [15] 崔希利，邢华斌. 金属有机框架材料分离低碳烃的研究进展. Journal, 2018, 69(6): 2339-2352 [16] Kyo Sung Park, Zheng N, Adrien P. Co#710; te #769;, Jae Yong Choi, Rudan Huang, Fernando J. Uribe-Romo, Hee K. Chae, Michael O#8217;Keeffe, and Omar M. Yaghi. Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. May 22, 2006

3. 毕业设计（论文）进程安排

起讫日期 设计（论文）各阶段工作内容 备 注 1.22-3.10 查阅文献，进行相关文献的翻译工作,完成开题报告。

3.11-3.31 了解zif-8的合成方法，探索新锌源用球磨法合成zif-8。

4.1-4.21 对已合成的zif-8测试xrd表征，对zif-8进行掺杂。