光/热引发法制备金属有机多面体聚合物任务书
2020-06-26 19:49:16
1. 毕业设计(论文)的内容和要求
毕业论文环节是大学学习的最后一个阶段,这一阶段需要我们将学习的基础理论和专业知识综合运用到课题的研究中,培养理论联系实际、严谨勤奋的工作态度和求实创新的科学作风,提高分析问题、解决问题和独立工作的能力。
希望同学珍惜学习机会,认真完成本课题的任务,具体要求如下: 1. 认真查阅与阅读文献,明确课题研究目的及所选择研究方法的依据,撰写开题报告,翻译一篇与课题相关的英文文献。
2. 开展实验,在实际操作过程中要能够分析并解决突发问题,能够对不同的实验结果进行分析对比; 3. 掌握实验中所用的表征仪器的分析原理、操作方法及mop聚合物材料的制备及性能研究的方法,学习表征实验的操作,学会使用各种实验所需仪器。
2. 参考文献
[1] Li Y T, Zhang D J, Gai F Y, et al. Ionic self-assembly of surface functionalized metal-organic polyhedra nanocages and their ordered honeycomb architecture at the air/water interface [J]. Chem. Commun., 2012,48, 7946-7948 [2] Kang Y H, Liu X D, Yan N, et al. Fabrication of Isolated Metal-Organic Polyhedra in Confined Cavities: Adsorbents/Catalysts with Unusual Dispersity and Activity[J]. Journal of the American Chemical Society., 2016, 138, 6099-102 [3] Lal G, Lee S J, Spasyuk D M. Amphiphile-like self assembly of metal organic polyhedra having both polar and non-polar groups [J]. Chem. Commun., 2018, 54, 1722-1725 [4] Liu Y, Wu X, He C, et al. Metal-organic polyhedra for selective sensing of ribonucleosides through the cooperation of hydrogen-bonding interactions [J] Dalton transactions., 2010, 39, 7727-32 [5] Pedersen C J. The Discovery of Crown Ethers (Noble Lecture) [J]. Angew. Chem., Int.Ed., 1988, 27:1021 - 1027. [6] Cram D J. The Design of Molecular Hosts, Guests and Their Complexes (Nobel Lecture) [J]. Angew. Chem.,Int. Ed., 1988,27:1009 - 1020. [7] Lehn J M. Supramolecular Chemistry--Scope and Perspectives Molecules, Supermolecules, and Molecular Devices (Nobel Lecture) [J], Angew. Chem., Int. Ed., 1988,27:89- 112. [8] 王结良,朱光明,梁国正,赵雯,吕生华. 自组装制备纳米材料的研究现状 [J]. 材料导报, 2003, 17(7): 67-69. [9] Liu S, Tang Z. Polyoxometalate-based functional nanostructured films: Current progressand future prospects [J]. Nano Today, 2010, 5(4): 267-281. [10] 李雁涛. 有机#8212;无机杂化纳米材料的组装及性能研究 [D].吉林大学,2012. [11] Zhao D, Tan S, Yuan D, et al. Surface Functionalization of Porous Coordination Nanocages Via Click Chemistry and Their Application in Drug Delivery [J]. Advanced Materials, 2011, 23(1): 90-93. [12] Furukawa H, Kim J, Ockwig N W, et al. Control of Vertex Geometry, Structure Dimensionality, Functionality and Pore Metrics in the Reticular Synthesis of Crystalline Metal#8722;Organic Frameworks and Polyhedra [J]. Journal of the American Chemical Society, 2008, 130(35): 11650-11661. [13] Jung M, Kim H, Beak K, et al. Synthetic Ion Channel Based on Metal#8211;Organic Polyhedra [J]. Angewandte Chemie International Edition, 2008, 47(31): 5755-5757. [14] Li J R, Timmons D J, Zhou H C. Interconversion between Molecular Polyhedra and Metal-Organic Frameworks [J]. Journal of the American Chemical Society, 2009, 131(18):6368-6369. [15] 焦扬. 金属有机多面体的组装及其功能化研究 [D].大连理工大学,2013. [16] Klein E, Ferrand Y, Barwell N P, et al. Solvent Effects in Carbohydrate Binding by Synthetic Receptors: Implications for the Role of Water in Natural Carbohydrate Recognition [J]. Angew. Chem. Int. Ed., 2008, 47(14): 2693-2696. [17] Ferrand Y, Crump M P, Davis A P. Synthetic Lectin Analog for Biomimetic Disaccharide Recognition [J]. Science, 2007, 318(5850): 619-624. [18] Li J R, Zhou H C. Bridging-Ligand-Substitution Strategy for the Preparation of Metal-Organic Polyhedra [J]. Nat. Chem., 2010, 2(10): 893-898. [19] Perryiv J J, Perman J A, Zaworotko M J. Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks [J]. Chemical Society Reviews, 2009, 38(5): 1400-1417. [20] Furukawa H, Kim J, Plass K E, et al. Crystal Structure, Dissolution, and Deposition of a 5 nm Functionalized Metal-Organic Great Rhombicuboctahedron [J]. Journal of the American Chemical Society, 2006, 128(26): 8398-8399.
3. 毕业设计(论文)进程安排
起讫日期 设计(论文)各阶段工作内容 备 注 2018.02.26-2018.03.10 查阅国内外有关文献,做文献综述;完成外文翻译;拟定实验方案。
2018.03.10-2018.05.20 按照实验要求进行各种实验工作。
2018.05.20-2018.06.01 进行实验数据的处理,补充有关实验,开始撰写论文。
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