1. 毕业设计（论文）的内容和要求

吸附制冷是利用固体吸附剂对吸附质（制冷剂）的吸附过程而获得冷量， 可用太阳能或工业余热等低品位热能驱动，具有节能和环保两大优势。

本课题主要针对对mofs材料经改性与异丁烷组成工质对，拟采用合成中以及合成后修饰的方法来对mil-101进行改性，以提高其对异丁烷的吸附性能。

要求： 1. 遵守实验室内的规章制度，保持实验室卫生，爱护实验仪器。

2. 参考文献

[1] 王如竹，王丽伟，吴静怡. 吸附式制冷理论与应用 [M]. 北京: 科学出版社, 2007. [2] Ismail A B, Li A, Thu K, et al. Pressurized adsorption cooling cycles driven by solar/waste heat[J]. Applied Thermal Engineering, 2014, 67(s 1#8211;2):106-113. [3] Chen H J, Yao X L, Cui Q, et al. Selection and performance of adsorbents in an adsorption refrigeration cycle regenerated with water directly[J]. Adsorption-journal of the International Adsorption Society, 2013, 19(5):997-1006. [4] 吴珅, et al. "油气/水蒸气在 TMCS 改性 MIL-101 (Cr) 上的吸附性能研究." 高校化学工程学报 4 (2016): 814-821. [5] Mhaisagar, Yogesh S., Bhavana N. Joshi, and A. M. Mahajan. "Surface texture modification of spin-coated SiO 2 xerogel thin films by TMCS silylation." Bulletin of Materials Science 35.2 (2012): 151-155. [6] Teo, How Wei Benjamin, Anutosh Chakraborty, and Sibnath Kayal. "Post synthetic modification of MIL-101 (Cr) for S-shaped isotherms and fast kinetics with water adsorption."Applied Thermal Engineering 120 (2017): 453-462. [7] Akiyama, George, et al. "Effect of functional groups in MIL-101 on water sorption behavior." Microporous and Mesoporous Materials 157 (2012): 89-93. [8] Ko, Nakeun, et al. "Tailoring the water adsorption properties of MIL-101 metal#8211;organic frameworks by partial functionalization." Journal of Materials Chemistry A 3.5 (2015): 2057-2064.

3. 毕业设计（论文）进程安排

2018-02-26#8212;03-10 查阅国内外有关文献，做文献综述；拟订实验方案。

2018-03-11#8212;04-26 按照实验要求进行各种实验工作。

2018-04-27#8212;05-23 进行实验数据的处理，开始撰写论文。