1. 毕业设计（论文）的内容和要求

研究内容主要为通过水热合成法，以p123为模板剂，teos为硅源合成sba-15介孔材料，并在其合成过程中，通过硅烷偶联剂γ-巯丙基三甲氧基硅与金属之间的配位作用将金纳米颗粒引入到sba-15材料的孔道中，从而改善其催化性能。

要求：需要本科生对整个催化剂的构造体系有一个清楚地认识，并能后从机理上理解介孔分子筛的组装机理。

同时对本科生独立的实验能力有一个考察。

2. 参考文献

[1] Kong Y, Zhang R, XU X J, et al. Synthesis and Characterization of V-MCM41 with High Vanadium Content [J]. Chinese J Inorg Chem, 2008, (24):1124-1127. [2] Wang Y, Zhang Q H, Ohishi Y, et al. Synthesis of V-MCM-41 by Template-Ion Exchange Method and Its Catalytic Properties in Propane Oxidative Dehydrogenation[J]. Catal Lett. 2001, 72 (3-4):215~219. [3] Huo Q, Margolese D I, Ciesla U, et al. Organization of organic molecules with inorganic molecular species into nanocomposite biphase arrays[J]. Chem Mater, 1994, 6 [4] Chen S Y, Tang C Y, Chuang W T, et al. A facile route to synthesizing functionalized mesoporous SBA-15 materials with platelet morphology and short mesochannels[J]. Chem Mater, 2008, 20 (12): 3906-3916. [5] Huo Q, Margolese D I, Ciesla U. Generalized synthesis of periodic surfactant/inorganic composite materials[J]. Nature, 1994, 368:317-321. [6] Liu X, Tian B, Yu C, et al. Room-Temperature Synthesis in Acidic Media of Large-Pore Three-Dimensional Bicontinuous Mesoporous Silica with Ia3d Symmetry[J]. Angew. Chem .Int. Edit. 2010, 41 (20): 3876~3878. [7] Nie D X, Liang Y, Zhou, T S, et al. FDU-15-Pt Composites with Different Pt Loading and Their Electrocatalytic Reduction to Ultratrace Nitroaromatic Compounds[J]. Int J Environ An Ch. 2012, 7(92): 832~843. [8] Tozuka Y, Wongmekiat A , Kimura K, et al. Effect of Pore Size of FSM-16 on The Entrapment of Flurbiprofen in Mesoporous Structures[J]. Chem Pharm Bull.2005,53(8): 974~977. [9] Jin D F, Hu G B, Jin H X, et al. Synthesis of Sulfated Zirconia by Grafting on Mesoporous SBA-15 by Sol-Gel Method[J]. Rare Metal Mat Eng , 2012, 41(53): 379~382.

3. 毕业设计（论文）进程安排

2017-02-20#8212;03-10 查阅国内外有关文献，拟订实验方案。 2017-03-10#8212;03-20 翻译外文文献，并撰写文献综述。 2017-03-20#8212;04-10 按照拟定的实验方案依次进行实验。 2017-04-10#8212;04-30 处理试验数据，分析结果。 2017-04-30#8212;05-10 进行实验数据的汇总整理，开始撰写论文。 2017-05-11#8212;06-12 完成论文，准备答辩。