1. 毕业设计（论文）的内容和要求

本课题要求在查阅文献的基础上，使用XRD、XPS、SEM、BET等表征手段及电化学工作站等研究手段，对多种镍基钙钛矿氧化物的电催化析氢反应（Hydrogen Evolution Reaction，HER）的性能进行较为系统的研究，从而为新型高效HER电催化剂的开发和优化提供指导。

课题要求： 1、检索和阅读与课题相关的文献资料； 2、多种镍基钙钛矿氧化物催化材料的合成及相应的结构表征； 3、掌握旋转圆盘（环盘）电极技术及电极制备工艺； 4、采用电化学工作站分析镍基钙钛矿氧化物对HER的电催化性能。

2. 参考文献

[1] Suntivich J, May K J, Gasteiger H A, Goodenough J B, Shao-Horn Y. A Perovskite Oxide Optimized for Oxygen Evolution Catalysis from Molecular Orbital Principles [J]. Science. 2011，334(6061):1383-1385． [2] Xu X, Chen Y, Zhou W, Zhu Z, Su C, Liu M, Shao Z. A perovskite electrocatalyst for efficient hydrogen evolution reaction [J]. Adv. Mater. 2016, 28(30): 6442-6448. [3] Jin H, Wang J, Su D, Wei Z, Pang Z, Wang Y. In situ cobalt#8211;cobalt oxide/N-doped carbon hybrids as superior bifunctional electrocatalysts for hydrogen and oxygen evolution [J]. J. Am. Chem. Soc. 2015,.137(7): 2688-2694. [4] Gong M, Zhou W, Tsai M-C, Zhou J, Guan M, Lin M-C, Zhang B, Hu Y, Wang D-Y, Yang J, Pennycook S J, Hwang B-J, Dai H. Nanoscale nickel oxide/nickel heterostructures for active hydrogen evolution electrocatalysis [J]. Nat. Commun. 2014, 5: 4695. [5] Vrubel H, Hu X. Molybdenum boride and carbide catalyze hydrogen evolution in both acidic and basic solutions [J]. Angew. Chem. Int. Ed. 2012, 51(51): 12703-1270. [6] Benck J D, Hellstern T R, Kibsgaard J, Chakthranont P, Jaramillo T F. Catalyzing the hydrogen evolution reaction (HER) with molybdenum sulfide nanomaterials [J]. ACS Catal. 2014, 4(11): 3957-3971. [7] Wang J, Cui W, Liu Q, Xing Z, Asiri A M, Sun X. Recent Progress in Cobalt-Based Heterogeneous Catalysts for Electrochemical Water Splitting [J]. AdV. Mater. 2016, 28(2): 215-230. [8] Chen D, Chen C, Baiyee Z M, Shao Z, Ciucci F. Nonstoichiometric oxides as low-cost and highly-efficient oxygen reduction/evolution catalysts for low-temperature electrochemical devices [J]. Chem. Rev. 2015, 115(18): 9869-9921.

3. 毕业设计（论文）进程安排

1-3周：阅读文献并撰写文献综述；学习实验安全知识及操作规范； 4-6周：熟悉实验室环境和仪器；学习并练习实验操作及仪器使用； 7-10周：合成镍基钙钛矿氧化物催化剂材料；采用XRD、XPS、SEM、BET等表征手段对粉体的理化性质进行表征； 11-14周：采用旋转圆盘（环盘）电极技术测试镍基钙钛矿氧化物粉体催化HER反应的电化学性能；分析、处理及汇总实验数据； 15-17周：撰写毕业论文，准备答辩。