登录

  • 登录
  • 忘记密码?点击找回

注册

  • 获取手机验证码 60
  • 注册

找回密码

  • 获取手机验证码60
  • 找回
毕业论文网 > 任务书 > 环境科学与工程类 > 环境工程 > 正文

表面修饰对MOFs封装MNPs的影响任务书

 2020-04-17 20:29:32  

1. 毕业设计(论文)的内容和要求

金属有机骨架(mofs)是一类新型的无机-有机杂化多孔材料,主要由芳香酸或碱的氮、氧多齿有机配体,通过配位键与无机金属中心杂化形成的立体网络结构晶体。

与其他传统多孔材料相比,mofs具有大孔隙率、高比表面积、结构多样性等特点。

此外,由于 mofs的金属离子和有机配体选择性多的特点,研究者们可根据需求选择不同尺寸、不同种类、不同官能团的有机链和金属离子以适应需求。

剩余内容已隐藏,您需要先支付后才能查看该篇文章全部内容!

2. 参考文献

[1] Stock N, Biswas S. Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites[J]. Chemical Reviews, 2012, 112(2): 933-969. [2] Maurin G, Serre C, Cooper A, et al. The new age of MOFs and of their porous-related solids[J]. Chemical Society Reviews, 2017, 46(11): 3104-3107. [3] Liu L J, Telfer S G. Systematic Ligand Modulation Enhances the Moisture Stability and Gas Sorption Characteristics of Quaternary Metal-Organic Frameworks[J]. Journal of the American Chemical Society, 2015, 137(11): 3901-3909. [4] An J, Geib S J, Rosi N L. Cation-Triggered Drug Release from a Porous Zinc#8722;Adeninate Metal#8722;Organic Framework[J]. Journal of the American Chemical Society, 2009, 131(24): 8376-8377. [5] Lee J, Farha O K, Roberts J, et al. Metal-organic framework materials as catalysts[J]. Chemical Society Reviews, 2009, 38(5): 1450-1459. [6] Wiersum A D, Gioyannangeli C, Vincent D, et al. Experimental Screening of Porous Materials for High Pressure Gas Adsorption and Evaluation in Gas Separations: Application to MOFs (MIL-100 and CAU-10)[J]. ACS Combinatorial Science, 2013, 15(2): 111-119. [7] Li J R, Kuppler R J, Zhou H C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chemical Society Reviews, 2009, 38(5): 1477-1504. [8] Gao C, Wang J, Xu H X, et al. Coordination chemistry in the design of heterogeneous photocatalysts[J]. Chemical Society Reviews, 2017, 46(10): 2799-2823. [9] Mounfield W P, Claure M T, Agrawal P K, et al. Synergistic Effect of Mixed Oxide on the Adsorption of Ammonia with Metal-Organic Frameworks[J]. Industrial Engineering Chemistry Research, 2016, 55(22): 6492-6500. [10] Britt D, Tranchemontagne D, Yaghi O M. Metal-organic frameworks with high capacity and selectivity for harmful gases[J]. Proceedings Of the National Academy Of Sciences Of the United States Of America, 2008, 105(33): 11623-11627. [11] Vellingiri K, Szulejko J E, Kumar P, et al. Metal organic frameworks as sorption media for volatile and semi-volatile organic compounds at ambient conditions[J]. Scientific Reports, 2016, 6: 27813. [12] Shi L, Wang T, Zhang H, et al. Electrostatic Self-Assembly of Nanosized Carbon Nitride Nanosheet onto a Zirconium Metal-Organic Framework for Enhanced Photocatalytic CO2Reduction[J]. Advanced Functional Materials, 2015, 25(33): 5360-5367. [13] Sheng H, Chen D, Li N, et al. Urchin-Inspired TiO2@MIL-101 Double-Shell Hollow Particles: Adsorption and Highly Efficient Photocatalytic Degradation of Hydrogen Sulfide[J]. Chemistry of Materials, 2017, 29(13): 5612-5616. 51-53 [14] Li X, Pi Y, Xia Q, et al. TiO2encapsulated in Salicylaldehyde-NH2 -MIL-101(Cr) for enhanced visible light-driven photodegradation of MB[J]. Applied Catalysis B: Environmental, 2016, 191: 192-201. [15] Zhang H, Jin M, Xia Y. Enhancing the catalytic and electrocatalytic properties of Pt-based catalysts by forming bimetallic nanocrystals with Pd[J]. Chemical Society Reviews, 2012, 41(24): 8035. [16] You H, Yang S, Ding B, et al. Synthesis of colloidal metal and metal alloy nanoparticles for electrochemical energy applications[J]. Chemical Society Reviews, 2013, 42(7): 2880-2904. [17] Zlotea C, Campesi R, Cuevas F, et al. Pd Nanoparticles Embedded into a Metal-Organic Framework: Synthesis, Structural Characteristics, and Hydrogen Sorption Properties[J]. Journal of the American Chemical Society, 2010, 132(9): 2991-2997. [18] Hwang Y K, Hong D-Y, Chang J-S, et al. Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation[J]. Angewandte Chemie International Edition, 2008, 47(22): 4144-4148. [19] Aijaz A, Karkamkar A, Choi Y J, et al. Immobilizing Highly Catalytically Active Pt Nanoparticles inside the Pores of Metal#8211;Organic Framework: A Double Solvents Approach[J]. Journal of the American Chemical Society, 2012, 134(34): 13926-13929. [20] Sun D, Li Z. Double-Solvent Method to Pd Nanoclusters Encapsulated inside the Cavity of NH2#8211;Uio-66(Zr) for Efficient Visible-Light-Promoted Suzuki Coupling Reaction[J]. The Journal of Physical Chemistry C, 2016, 120(35): 19744-19750. [21] Esken D, Turner S, Lebedev O I, et al. Au@ZIFs: Stabilization and Encapsulation of Cavity-Size Matching Gold Clusters inside Functionalized Zeolite Imidazolate Frameworks, ZIFs[J]. Chemistry of Materials, 2010, 22(23): 6393-6401. [22] Jiang H-L, Liu B, Akita T, et al. Au@ZIF-8: CO Oxidation over Gold Nanoparticles Deposited to Metal#8722;Organic Framework[J]. Journal of the American Chemical Society, 2009, 131(32): 11302-11303.

3. 毕业设计(论文)进程安排

起讫日期 设计(论文)各阶段工作内容 备注 2019.1~2019.3 查阅文献,撰写文献综述和开题报告,并修改开题报告。

2019.3~2019.5 实验阶段(制定实验步骤、实验方案、实验、分析实验数据、补充实验) 2019.5~2019.6.10 撰写论文、修改论文,准备答辩。

剩余内容已隐藏,您需要先支付 5元 才能查看该篇文章全部内容!立即支付

微信号:bysjorg

Copyright © 2010-2022 毕业论文网 站点地图