N型萘二酰亚胺稠杂环芳烃合成及其光电性质研究任务书
2020-04-30 16:13:05
1. 毕业设计(论文)的内容和要求
新一代柔性电子消费品将慢慢步入人类的日常生活,给人们的生活、工作带来翻天覆地的变化。
据英国高增长市场预测,柔性电子产品的全球市场销售总额至2029年将高达3350亿美元,其中最具增长潜力的有柔性有源驱动显示、有机传感、有机射频标签等领域,而这些领域中,对n型有机半导体的需求非常迫切。
迄今为止,高性能的p型有机半导体材料数量远多于n型材料,n型有机半导体材料尤其短缺。
2. 参考文献
1. F. Zhang, Y. Hu, T. Schuettfort, C-A. Di, X. Gao, C. R. McNeill, L. Thomsen, S. C. B. Mannsfeld, W. Yuan, H. Sirringhaus, D. Zhu. Critical Role of Alkyl Chain Branching of Organic Semiconductors in Enabling Solution-Processed N#8209;Channel Organic Thin-Film Transistors with Mobility of up to 3.50 cm2 V#8722;1 s#8722;1. J. Am. Chem. Soc. 2013, 135, 2338#8722;2349. 2. C. Wang, H. Dong, W. Hu, Y. Liu, D. Zhu. Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics. Chem. Rev. 2012, 112, 2208#8211;2267. 3. H. Yan, Z. Chen, Y. Zheng, C. Newman, J. R. Quinn, F. Douml;tz, M. Kastler, A. Facchetti. A high-mobility electron-transporting polymer for printed transistors. Nature, 2009, 457, 679-686. 4. Z. Liu, G. Zhang, Z. Cai, X. Chen, H. Luo, Y. Li, J. Wang, D. Zhang. New Organic Semiconductors with Imide/Amide-Containing Molecular Systems. Adv. Mater. 2014, 26, 6965#8211;6977. 5. Xing G, Mathews N, Lim S S, et al. Low-temperature solution-processed wavelength-tunable perovskites for lasing. Nat Materials, 2014, 13: 476. 6. Shao J, Chang J, Chi C. Solution-processable n-type semiconductors based on unsymmetrical naphthalene imides: synthesis, characterization, and applications in field-effect transistors. Chem#8211;Asian J, 2014, 9: 253-260. 7. Yang C, Cho S, Chiechi R C, et al. Visible-near infrared absorbing dithienylcyclopentadienone-thiophene copolymers for organic thin-film transistors. J.Am Chem Soc, 2008, 130: 16524-16526. 8. Ding L, Li H #8211;B, Lei T, et al. Alkylene-Chain Effect on Microwire Growth and Crystal Packing of π-Moieties. Chem Mater, 2012, 24: 1944-1949. 9. Ding L, Ying H -Z, Zhou Y, Lei T, Pei J. Polycyclic Imide Derivatives: Synthesis and Effective Tuning of Lowest Unoccupied Molecular Orbital Levels through Molecular Engineering. Org Lett, 2012, 12: 5522-5525. 10. Shao J, Chang J, Chi C, Linear and star-shaped pyrazine-containing acene dicarboximides with high electron-affinity. Org Biomol Chem, 2012, 10: 7045-7052. 11. Ding L, Yang C, Su Z, Pei J. Synthesis, crystal structure, and application of an acenaphtho[1,2-k] fluoranthene diimide derivative. Sci China Chem, 2015, 58: 364-369. 12. Shi X, Liu S, Liu C, et al. Highly Contorted 1,2,5-Thiadiazole-Fused Aromatics for Solution-Processed Field-Effect Transistors: Synthesis and Properties. Chem.#8211;Asian J, 2016, 11: 2188-2200.
3. 毕业设计(论文)进程安排
每周六天,每天8-10小时。
1、第1-4周:文献阅读,了解相关领域的研究动态,课题背景;学习实验室安全知识。
2、第5-8周:学习实验室安全知识;进入实验室学习。
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